Bis[2-(1H-benzotriazol-1-yl)acetonitrile-κN (3)]dibromidocopper(II)

In the title complex, [CuBr(2)(C(8)H(6)N(4))(2)], the Cu(II) atom is located on an inversion centre and the asymmetric unit comprises one half-mol­ecule. The Cu atom is coordinated by two Br ions and two N atoms in approximately square-planar geometry. In the crystal structure, inter­molecular C—H⋯B...

Descripción completa

Detalles Bibliográficos
Autor principal: Wang, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961923/
https://www.ncbi.nlm.nih.gov/pubmed/21203092
http://dx.doi.org/10.1107/S1600536808019260
_version_ 1782189098367188992
author Wang, Wei
author_facet Wang, Wei
author_sort Wang, Wei
collection PubMed
description In the title complex, [CuBr(2)(C(8)H(6)N(4))(2)], the Cu(II) atom is located on an inversion centre and the asymmetric unit comprises one half-mol­ecule. The Cu atom is coordinated by two Br ions and two N atoms in approximately square-planar geometry. In the crystal structure, inter­molecular C—H⋯Br hydrogen bonds and π–π inter­actions between benzotriazole rings (centroid–centroid distance = 3.651 Å) generate a three-dimensional network.
format Text
id pubmed-2961923
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29619232010-12-30 Bis[2-(1H-benzotriazol-1-yl)acetonitrile-κN (3)]dibromidocopper(II) Wang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuBr(2)(C(8)H(6)N(4))(2)], the Cu(II) atom is located on an inversion centre and the asymmetric unit comprises one half-mol­ecule. The Cu atom is coordinated by two Br ions and two N atoms in approximately square-planar geometry. In the crystal structure, inter­molecular C—H⋯Br hydrogen bonds and π–π inter­actions between benzotriazole rings (centroid–centroid distance = 3.651 Å) generate a three-dimensional network. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2961923/ /pubmed/21203092 http://dx.doi.org/10.1107/S1600536808019260 Text en © Wei Wang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Wei
Bis[2-(1H-benzotriazol-1-yl)acetonitrile-κN (3)]dibromidocopper(II)
title Bis[2-(1H-benzotriazol-1-yl)acetonitrile-κN (3)]dibromidocopper(II)
title_full Bis[2-(1H-benzotriazol-1-yl)acetonitrile-κN (3)]dibromidocopper(II)
title_fullStr Bis[2-(1H-benzotriazol-1-yl)acetonitrile-κN (3)]dibromidocopper(II)
title_full_unstemmed Bis[2-(1H-benzotriazol-1-yl)acetonitrile-κN (3)]dibromidocopper(II)
title_short Bis[2-(1H-benzotriazol-1-yl)acetonitrile-κN (3)]dibromidocopper(II)
title_sort bis[2-(1h-benzotriazol-1-yl)acetonitrile-κn (3)]dibromidocopper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961923/
https://www.ncbi.nlm.nih.gov/pubmed/21203092
http://dx.doi.org/10.1107/S1600536808019260
work_keys_str_mv AT wangwei bis21hbenzotriazol1ylacetonitrilekn3dibromidocopperii

Ejemplares similares