Diaqua­bis[5-(2-pyridylmeth­yl)tetra­zolato-κ(2) N (1),N (5)]manganese(II)

The title complex, [Mn(C(7)H(6)N(5))(2)(H(2)O)(2)], was obtained by the in situ hydro­thermal reaction of MnCl(2) with 2-(2-pyrid­yl)acetonitrile in the presence of NaN(3). The Mn(II) atom, which is located on an inversion centre, has a distorted octa­hedral coordination geometry formed by two water...

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Detalles Bibliográficos
Autor principal: Wang, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961924/
https://www.ncbi.nlm.nih.gov/pubmed/21203093
http://dx.doi.org/10.1107/S1600536808019272
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author Wang, Wei
author_facet Wang, Wei
author_sort Wang, Wei
collection PubMed
description The title complex, [Mn(C(7)H(6)N(5))(2)(H(2)O)(2)], was obtained by the in situ hydro­thermal reaction of MnCl(2) with 2-(2-pyrid­yl)acetonitrile in the presence of NaN(3). The Mn(II) atom, which is located on an inversion centre, has a distorted octa­hedral coordination geometry formed by two water mol­ecules and two chelating ligands. Inter­molecular hydrogen bonds and π–π inter­actions (3.452 Å) stabilize the crystal structure and lead to the formation of a three-dimensional network.
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spelling pubmed-29619242010-12-30 Diaqua­bis[5-(2-pyridylmeth­yl)tetra­zolato-κ(2) N (1),N (5)]manganese(II) Wang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Mn(C(7)H(6)N(5))(2)(H(2)O)(2)], was obtained by the in situ hydro­thermal reaction of MnCl(2) with 2-(2-pyrid­yl)acetonitrile in the presence of NaN(3). The Mn(II) atom, which is located on an inversion centre, has a distorted octa­hedral coordination geometry formed by two water mol­ecules and two chelating ligands. Inter­molecular hydrogen bonds and π–π inter­actions (3.452 Å) stabilize the crystal structure and lead to the formation of a three-dimensional network. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2961924/ /pubmed/21203093 http://dx.doi.org/10.1107/S1600536808019272 Text en © Wei Wang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Wei
Diaqua­bis[5-(2-pyridylmeth­yl)tetra­zolato-κ(2) N (1),N (5)]manganese(II)
title Diaqua­bis[5-(2-pyridylmeth­yl)tetra­zolato-κ(2) N (1),N (5)]manganese(II)
title_full Diaqua­bis[5-(2-pyridylmeth­yl)tetra­zolato-κ(2) N (1),N (5)]manganese(II)
title_fullStr Diaqua­bis[5-(2-pyridylmeth­yl)tetra­zolato-κ(2) N (1),N (5)]manganese(II)
title_full_unstemmed Diaqua­bis[5-(2-pyridylmeth­yl)tetra­zolato-κ(2) N (1),N (5)]manganese(II)
title_short Diaqua­bis[5-(2-pyridylmeth­yl)tetra­zolato-κ(2) N (1),N (5)]manganese(II)
title_sort diaqua­bis[5-(2-pyridylmeth­yl)tetra­zolato-κ(2) n (1),n (5)]manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961924/
https://www.ncbi.nlm.nih.gov/pubmed/21203093
http://dx.doi.org/10.1107/S1600536808019272
work_keys_str_mv AT wangwei diaquabis52pyridylmethyltetrazolatok2n1n5manganeseii

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