Tris(tert-butyl isocyanide-κC)carbonylnickel(0)

The title compound, [Ni(C(5)H(9)N)(3)(CO)], was prepared from Ni(CO)(4) and a tenfold excess of tert-butyl isocyanide. It crystallizes with two symmetry-independent mol­ecules per asymmetric unit. The central Ni atom of each independent mol­ecule has a nearly perfect tetra­hedral coordination enviro...

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Detalles Bibliográficos
Autores principales: Imhof, Wolfgang, Görls, Helmar, Halbauer, Kathi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961925/
https://www.ncbi.nlm.nih.gov/pubmed/21202996
http://dx.doi.org/10.1107/S1600536808020138
Descripción
Sumario:The title compound, [Ni(C(5)H(9)N)(3)(CO)], was prepared from Ni(CO)(4) and a tenfold excess of tert-butyl isocyanide. It crystallizes with two symmetry-independent mol­ecules per asymmetric unit. The central Ni atom of each independent mol­ecule has a nearly perfect tetra­hedral coordination environment, comprising one carbon monoxide and three isocyanide ligands. The title compound is the first structurally characterized Ni(0) compound with a mixed CO/RNC coordination.

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