Tris(tert-butyl isocyanide-κC)carbonylnickel(0)

The title compound, [Ni(C(5)H(9)N)(3)(CO)], was prepared from Ni(CO)(4) and a tenfold excess of tert-butyl isocyanide. It crystallizes with two symmetry-independent mol­ecules per asymmetric unit. The central Ni atom of each independent mol­ecule has a nearly perfect tetra­hedral coordination enviro...

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Detalles Bibliográficos
Autores principales: Imhof, Wolfgang, Görls, Helmar, Halbauer, Kathi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961925/
https://www.ncbi.nlm.nih.gov/pubmed/21202996
http://dx.doi.org/10.1107/S1600536808020138
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author Imhof, Wolfgang
Görls, Helmar
Halbauer, Kathi
author_facet Imhof, Wolfgang
Görls, Helmar
Halbauer, Kathi
author_sort Imhof, Wolfgang
collection PubMed
description The title compound, [Ni(C(5)H(9)N)(3)(CO)], was prepared from Ni(CO)(4) and a tenfold excess of tert-butyl isocyanide. It crystallizes with two symmetry-independent mol­ecules per asymmetric unit. The central Ni atom of each independent mol­ecule has a nearly perfect tetra­hedral coordination environment, comprising one carbon monoxide and three isocyanide ligands. The title compound is the first structurally characterized Ni(0) compound with a mixed CO/RNC coordination.
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spelling pubmed-29619252010-12-30 Tris(tert-butyl isocyanide-κC)carbonylnickel(0) Imhof, Wolfgang Görls, Helmar Halbauer, Kathi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(5)H(9)N)(3)(CO)], was prepared from Ni(CO)(4) and a tenfold excess of tert-butyl isocyanide. It crystallizes with two symmetry-independent mol­ecules per asymmetric unit. The central Ni atom of each independent mol­ecule has a nearly perfect tetra­hedral coordination environment, comprising one carbon monoxide and three isocyanide ligands. The title compound is the first structurally characterized Ni(0) compound with a mixed CO/RNC coordination. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2961925/ /pubmed/21202996 http://dx.doi.org/10.1107/S1600536808020138 Text en © Imhof et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Imhof, Wolfgang
Görls, Helmar
Halbauer, Kathi
Tris(tert-butyl isocyanide-κC)carbonylnickel(0)
title Tris(tert-butyl isocyanide-κC)carbonylnickel(0)
title_full Tris(tert-butyl isocyanide-κC)carbonylnickel(0)
title_fullStr Tris(tert-butyl isocyanide-κC)carbonylnickel(0)
title_full_unstemmed Tris(tert-butyl isocyanide-κC)carbonylnickel(0)
title_short Tris(tert-butyl isocyanide-κC)carbonylnickel(0)
title_sort tris(tert-butyl isocyanide-κc)carbonylnickel(0)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961925/
https://www.ncbi.nlm.nih.gov/pubmed/21202996
http://dx.doi.org/10.1107/S1600536808020138
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AT gorlshelmar tristertbutylisocyanidekccarbonylnickel0
AT halbauerkathi tristertbutylisocyanidekccarbonylnickel0

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