(E)-1-Ferrocenyl-3-phenyl­prop-2-en-1-one

The title compound, [Fe(C(5)H(5))(C(14)H(11)O)], exists as the E isomer, and the substituent is fully conjugated with the attached five-membered ring. In the ferrocene unit, the substituted cyclo­penta­dienyl ring (Cps) plane and unsubstituted cyclo­penta­dienyl ring (Cp) plane are almost parallel,...

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Detalles Bibliográficos
Autores principales: Liu, Yong-Hong, Liu, Jian-Feng, Jian, Pan-Ming, Liu, Xiao-Lan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961926/
https://www.ncbi.nlm.nih.gov/pubmed/21202997
http://dx.doi.org/10.1107/S1600536808020059
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author Liu, Yong-Hong
Liu, Jian-Feng
Jian, Pan-Ming
Liu, Xiao-Lan
author_facet Liu, Yong-Hong
Liu, Jian-Feng
Jian, Pan-Ming
Liu, Xiao-Lan
author_sort Liu, Yong-Hong
collection PubMed
description The title compound, [Fe(C(5)H(5))(C(14)H(11)O)], exists as the E isomer, and the substituent is fully conjugated with the attached five-membered ring. In the ferrocene unit, the substituted cyclo­penta­dienyl ring (Cps) plane and unsubstituted cyclo­penta­dienyl ring (Cp) plane are almost parallel, and the C atoms in Cp and Cps are in an eclipsed conformation. In the crystal structure, mol­ecules are linked into C(5) chains via inter­molecular C—H⋯O hydrogen bonds, and neighbouring chains are assembled into sheets by inter­molecular C—H⋯π(arene) hydrogen bonds along the c axis.
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spelling pubmed-29619262010-12-30 (E)-1-Ferrocenyl-3-phenyl­prop-2-en-1-one Liu, Yong-Hong Liu, Jian-Feng Jian, Pan-Ming Liu, Xiao-Lan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(5)H(5))(C(14)H(11)O)], exists as the E isomer, and the substituent is fully conjugated with the attached five-membered ring. In the ferrocene unit, the substituted cyclo­penta­dienyl ring (Cps) plane and unsubstituted cyclo­penta­dienyl ring (Cp) plane are almost parallel, and the C atoms in Cp and Cps are in an eclipsed conformation. In the crystal structure, mol­ecules are linked into C(5) chains via inter­molecular C—H⋯O hydrogen bonds, and neighbouring chains are assembled into sheets by inter­molecular C—H⋯π(arene) hydrogen bonds along the c axis. International Union of Crystallography 2008-07-05 /pmc/articles/PMC2961926/ /pubmed/21202997 http://dx.doi.org/10.1107/S1600536808020059 Text en © Liu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Yong-Hong
Liu, Jian-Feng
Jian, Pan-Ming
Liu, Xiao-Lan
(E)-1-Ferrocenyl-3-phenyl­prop-2-en-1-one
title (E)-1-Ferrocenyl-3-phenyl­prop-2-en-1-one
title_full (E)-1-Ferrocenyl-3-phenyl­prop-2-en-1-one
title_fullStr (E)-1-Ferrocenyl-3-phenyl­prop-2-en-1-one
title_full_unstemmed (E)-1-Ferrocenyl-3-phenyl­prop-2-en-1-one
title_short (E)-1-Ferrocenyl-3-phenyl­prop-2-en-1-one
title_sort (e)-1-ferrocenyl-3-phenyl­prop-2-en-1-one
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961926/
https://www.ncbi.nlm.nih.gov/pubmed/21202997
http://dx.doi.org/10.1107/S1600536808020059
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AT jianpanming e1ferrocenyl3phenylprop2en1one
AT liuxiaolan e1ferrocenyl3phenylprop2en1one

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