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2,2′-Biimidazolium hexaaquamanganese(II) bis(sulfate)
The title compound, (C(6)H(8)N(4))[Mn(H(2)O)(6)](SO(4))(2), was obtained by cocrystallization of 2,2′-biimidazolium sulfate and bis(tetrabutylammonium) tetrachloridomanganate(II). The asymmetric unit contains one isolated (SO(4))(2−) anion, one half of an octahedral [Mn(H(2)O)(6)](2+) dication...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961928/ https://www.ncbi.nlm.nih.gov/pubmed/21202999 http://dx.doi.org/10.1107/S1600536808020291 |
| _version_ | 1782189099540545536 |
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| author | Kurawa, Mukhtar A. Adams, Christopher J. Orpen, A. Guy |
| author_facet | Kurawa, Mukhtar A. Adams, Christopher J. Orpen, A. Guy |
| author_sort | Kurawa, Mukhtar A. |
| collection | PubMed |
| description | The title compound, (C(6)H(8)N(4))[Mn(H(2)O)(6)](SO(4))(2), was obtained by cocrystallization of 2,2′-biimidazolium sulfate and bis(tetrabutylammonium) tetrachloridomanganate(II). The asymmetric unit contains one isolated (SO(4))(2−) anion, one half of an octahedral [Mn(H(2)O)(6)](2+) dication and one half of a 2,2′-biimidazolium dication, each of which lies on an inversion centre. Molecules are connected by a three-dimensional N—H⋯O and O—H⋯O hydrogen-bond network. |
| format | Text |
| id | pubmed-2961928 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29619282010-12-30 2,2′-Biimidazolium hexaaquamanganese(II) bis(sulfate) Kurawa, Mukhtar A. Adams, Christopher J. Orpen, A. Guy Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(6)H(8)N(4))[Mn(H(2)O)(6)](SO(4))(2), was obtained by cocrystallization of 2,2′-biimidazolium sulfate and bis(tetrabutylammonium) tetrachloridomanganate(II). The asymmetric unit contains one isolated (SO(4))(2−) anion, one half of an octahedral [Mn(H(2)O)(6)](2+) dication and one half of a 2,2′-biimidazolium dication, each of which lies on an inversion centre. Molecules are connected by a three-dimensional N—H⋯O and O—H⋯O hydrogen-bond network. International Union of Crystallography 2008-07-09 /pmc/articles/PMC2961928/ /pubmed/21202999 http://dx.doi.org/10.1107/S1600536808020291 Text en © Kurawa et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kurawa, Mukhtar A. Adams, Christopher J. Orpen, A. Guy 2,2′-Biimidazolium hexaaquamanganese(II) bis(sulfate) |
| title | 2,2′-Biimidazolium hexaaquamanganese(II) bis(sulfate) |
| title_full | 2,2′-Biimidazolium hexaaquamanganese(II) bis(sulfate) |
| title_fullStr | 2,2′-Biimidazolium hexaaquamanganese(II) bis(sulfate) |
| title_full_unstemmed | 2,2′-Biimidazolium hexaaquamanganese(II) bis(sulfate) |
| title_short | 2,2′-Biimidazolium hexaaquamanganese(II) bis(sulfate) |
| title_sort | 2,2′-biimidazolium hexaaquamanganese(ii) bis(sulfate) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961928/ https://www.ncbi.nlm.nih.gov/pubmed/21202999 http://dx.doi.org/10.1107/S1600536808020291 |
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