Cargando…
catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymethyl)tetrazolato-κ(4) N (5),O,N (1):N (4)]
In the title compound, [Co(C(11)H(8)N(5)O)Cl](n), the Co(II) atom is pentacoordinated by one O atom and two N atoms from a 5-(8-quinolyloxymethyl)tetrazolate ligand, one N atom from another symmetry-related ligand, and a Cl atom. The coordination geometry can be described as slightly distorted tr...
Autores principales: | , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961929/ https://www.ncbi.nlm.nih.gov/pubmed/21203000 http://dx.doi.org/10.1107/S1600536808020205 |
Sumario: | In the title compound, [Co(C(11)H(8)N(5)O)Cl](n), the Co(II) atom is pentacoordinated by one O atom and two N atoms from a 5-(8-quinolyloxymethyl)tetrazolate ligand, one N atom from another symmetry-related ligand, and a Cl atom. The coordination geometry can be described as slightly distorted trigonal–bipyramidal. Adjacent Co atoms are connected by the bridging tetrazole groups into a chain. The dihedral angle between the quinoline and tetrazole planes is 21.2 (1)°. The structure involves intra- and interchain C—H⋯N hydrogen bonds. |
---|