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catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymethyl)tetrazolato-κ(4) N (5),O,N (1):N (4)]
In the title compound, [Co(C(11)H(8)N(5)O)Cl](n), the Co(II) atom is pentacoordinated by one O atom and two N atoms from a 5-(8-quinolyloxymethyl)tetrazolate ligand, one N atom from another symmetry-related ligand, and a Cl atom. The coordination geometry can be described as slightly distorted tr...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961929/ https://www.ncbi.nlm.nih.gov/pubmed/21203000 http://dx.doi.org/10.1107/S1600536808020205 |
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author | Wang, Guo-Xi Ye, Heng-Yun |
author_facet | Wang, Guo-Xi Ye, Heng-Yun |
author_sort | Wang, Guo-Xi |
collection | PubMed |
description | In the title compound, [Co(C(11)H(8)N(5)O)Cl](n), the Co(II) atom is pentacoordinated by one O atom and two N atoms from a 5-(8-quinolyloxymethyl)tetrazolate ligand, one N atom from another symmetry-related ligand, and a Cl atom. The coordination geometry can be described as slightly distorted trigonal–bipyramidal. Adjacent Co atoms are connected by the bridging tetrazole groups into a chain. The dihedral angle between the quinoline and tetrazole planes is 21.2 (1)°. The structure involves intra- and interchain C—H⋯N hydrogen bonds. |
format | Text |
id | pubmed-2961929 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29619292010-12-30 catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymethyl)tetrazolato-κ(4) N (5),O,N (1):N (4)] Wang, Guo-Xi Ye, Heng-Yun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(11)H(8)N(5)O)Cl](n), the Co(II) atom is pentacoordinated by one O atom and two N atoms from a 5-(8-quinolyloxymethyl)tetrazolate ligand, one N atom from another symmetry-related ligand, and a Cl atom. The coordination geometry can be described as slightly distorted trigonal–bipyramidal. Adjacent Co atoms are connected by the bridging tetrazole groups into a chain. The dihedral angle between the quinoline and tetrazole planes is 21.2 (1)°. The structure involves intra- and interchain C—H⋯N hydrogen bonds. International Union of Crystallography 2008-07-09 /pmc/articles/PMC2961929/ /pubmed/21203000 http://dx.doi.org/10.1107/S1600536808020205 Text en © Wang and Ye 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Guo-Xi Ye, Heng-Yun catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymethyl)tetrazolato-κ(4) N (5),O,N (1):N (4)] |
title |
catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymethyl)tetrazolato-κ(4)
N
(5),O,N
(1):N
(4)] |
title_full |
catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymethyl)tetrazolato-κ(4)
N
(5),O,N
(1):N
(4)] |
title_fullStr |
catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymethyl)tetrazolato-κ(4)
N
(5),O,N
(1):N
(4)] |
title_full_unstemmed |
catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymethyl)tetrazolato-κ(4)
N
(5),O,N
(1):N
(4)] |
title_short |
catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymethyl)tetrazolato-κ(4)
N
(5),O,N
(1):N
(4)] |
title_sort | catena-poly[[chloridocobalt(ii)]-μ-5-(8-quinolyloxymethyl)tetrazolato-κ(4)
n
(5),o,n
(1):n
(4)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961929/ https://www.ncbi.nlm.nih.gov/pubmed/21203000 http://dx.doi.org/10.1107/S1600536808020205 |
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