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catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymeth­yl)tetra­zolato-κ(4) N (5),O,N (1):N (4)]

In the title compound, [Co(C(11)H(8)N(5)O)Cl](n), the Co(II) atom is penta­coordinated by one O atom and two N atoms from a 5-(8-quinolyloxymeth­yl)tetra­zolate ligand, one N atom from another symmetry-related ligand, and a Cl atom. The coordination geometry can be described as slightly distorted tr...

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Detalles Bibliográficos
Autores principales: Wang, Guo-Xi, Ye, Heng-Yun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961929/
https://www.ncbi.nlm.nih.gov/pubmed/21203000
http://dx.doi.org/10.1107/S1600536808020205
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author Wang, Guo-Xi
Ye, Heng-Yun
author_facet Wang, Guo-Xi
Ye, Heng-Yun
author_sort Wang, Guo-Xi
collection PubMed
description In the title compound, [Co(C(11)H(8)N(5)O)Cl](n), the Co(II) atom is penta­coordinated by one O atom and two N atoms from a 5-(8-quinolyloxymeth­yl)tetra­zolate ligand, one N atom from another symmetry-related ligand, and a Cl atom. The coordination geometry can be described as slightly distorted trigonal–bipyramidal. Adjacent Co atoms are connected by the bridging tetra­zole groups into a chain. The dihedral angle between the quinoline and tetra­zole planes is 21.2 (1)°. The structure involves intra- and inter­chain C—H⋯N hydrogen bonds.
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spelling pubmed-29619292010-12-30 catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymeth­yl)tetra­zolato-κ(4) N (5),O,N (1):N (4)] Wang, Guo-Xi Ye, Heng-Yun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(11)H(8)N(5)O)Cl](n), the Co(II) atom is penta­coordinated by one O atom and two N atoms from a 5-(8-quinolyloxymeth­yl)tetra­zolate ligand, one N atom from another symmetry-related ligand, and a Cl atom. The coordination geometry can be described as slightly distorted trigonal–bipyramidal. Adjacent Co atoms are connected by the bridging tetra­zole groups into a chain. The dihedral angle between the quinoline and tetra­zole planes is 21.2 (1)°. The structure involves intra- and inter­chain C—H⋯N hydrogen bonds. International Union of Crystallography 2008-07-09 /pmc/articles/PMC2961929/ /pubmed/21203000 http://dx.doi.org/10.1107/S1600536808020205 Text en © Wang and Ye 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Guo-Xi
Ye, Heng-Yun
catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymeth­yl)tetra­zolato-κ(4) N (5),O,N (1):N (4)]
title catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymeth­yl)tetra­zolato-κ(4) N (5),O,N (1):N (4)]
title_full catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymeth­yl)tetra­zolato-κ(4) N (5),O,N (1):N (4)]
title_fullStr catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymeth­yl)tetra­zolato-κ(4) N (5),O,N (1):N (4)]
title_full_unstemmed catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymeth­yl)tetra­zolato-κ(4) N (5),O,N (1):N (4)]
title_short catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymeth­yl)tetra­zolato-κ(4) N (5),O,N (1):N (4)]
title_sort catena-poly[[chloridocobalt(ii)]-μ-5-(8-quinolyloxymeth­yl)tetra­zolato-κ(4) n (5),o,n (1):n (4)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961929/
https://www.ncbi.nlm.nih.gov/pubmed/21203000
http://dx.doi.org/10.1107/S1600536808020205
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