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Poly[diaqua-1κ(2) O-bis[μ(3)-2-(1H-tetrazol-5-yl)benzoato(2−)]dicadmium(II)]
The title compound, [Cd(2)(C(8)H(4)N(4)O(2))(2)(H(2)O)(2)](n), is a coordination polymer prepared by the hydrothermal reaction of cadmium(II) chloride and 2-(1H-tetrazol-5-yl)benzoic acid. Two types of coordinated cadmium cations exist in the structure. One is located on a twofold axis and is coor...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961931/ https://www.ncbi.nlm.nih.gov/pubmed/21203002 http://dx.doi.org/10.1107/S1600536808020503 |
Sumario: | The title compound, [Cd(2)(C(8)H(4)N(4)O(2))(2)(H(2)O)(2)](n), is a coordination polymer prepared by the hydrothermal reaction of cadmium(II) chloride and 2-(1H-tetrazol-5-yl)benzoic acid. Two types of coordinated cadmium cations exist in the structure. One is located on a twofold axis and is coordinated by four O and two N atoms from four symmetry-related ligands, forming a trigonal-prismatic coordination polyhedron. The other is located on an inversion center and is octahedrally coordinated by two N and two O atoms from two ligands in equatorial sites, and two water molecules in axial sites. The organic ligand bridges three Cd atoms, through a carboxylate group and two N atoms of the tetrazolate unit. This mode of coordination results in a two-dimensional framework. The crystal structure is stabilized by intermolecular O—H⋯O and O—H⋯N hydrogen bonds. |
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