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Poly[diaqua-1κ(2) O-bis[μ(3)-2-(1H-tetra­zol-5-yl)benzoato(2−)]dicadmium(II)]

The title compound, [Cd(2)(C(8)H(4)N(4)O(2))(2)(H(2)O)(2)](n), is a coordination polymer prepared by the hydro­thermal reaction of cadmium(II) chloride and 2-(1H-tetra­zol-5-yl)benzoic acid. Two types of coordinated cadmium cations exist in the structure. One is located on a twofold axis and is coor...

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Detalles Bibliográficos
Autores principales: Li, Xiu-Zhi, Wu, Bao-Zhen, Qu, Zhi-Rong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961931/
https://www.ncbi.nlm.nih.gov/pubmed/21203002
http://dx.doi.org/10.1107/S1600536808020503
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author Li, Xiu-Zhi
Wu, Bao-Zhen
Qu, Zhi-Rong
author_facet Li, Xiu-Zhi
Wu, Bao-Zhen
Qu, Zhi-Rong
author_sort Li, Xiu-Zhi
collection PubMed
description The title compound, [Cd(2)(C(8)H(4)N(4)O(2))(2)(H(2)O)(2)](n), is a coordination polymer prepared by the hydro­thermal reaction of cadmium(II) chloride and 2-(1H-tetra­zol-5-yl)benzoic acid. Two types of coordinated cadmium cations exist in the structure. One is located on a twofold axis and is coordinated by four O and two N atoms from four symmetry-related ligands, forming a trigonal-prismatic coordination polyhedron. The other is located on an inversion center and is octa­hedrally coordinated by two N and two O atoms from two ligands in equatorial sites, and two water mol­ecules in axial sites. The organic ligand bridges three Cd atoms, through a carboxyl­ate group and two N atoms of the tetra­zolate unit. This mode of coordination results in a two-dimensional framework. The crystal structure is stabilized by inter­molecular O—H⋯O and O—H⋯N hydrogen bonds.
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spelling pubmed-29619312010-12-30 Poly[diaqua-1κ(2) O-bis[μ(3)-2-(1H-tetra­zol-5-yl)benzoato(2−)]dicadmium(II)] Li, Xiu-Zhi Wu, Bao-Zhen Qu, Zhi-Rong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(2)(C(8)H(4)N(4)O(2))(2)(H(2)O)(2)](n), is a coordination polymer prepared by the hydro­thermal reaction of cadmium(II) chloride and 2-(1H-tetra­zol-5-yl)benzoic acid. Two types of coordinated cadmium cations exist in the structure. One is located on a twofold axis and is coordinated by four O and two N atoms from four symmetry-related ligands, forming a trigonal-prismatic coordination polyhedron. The other is located on an inversion center and is octa­hedrally coordinated by two N and two O atoms from two ligands in equatorial sites, and two water mol­ecules in axial sites. The organic ligand bridges three Cd atoms, through a carboxyl­ate group and two N atoms of the tetra­zolate unit. This mode of coordination results in a two-dimensional framework. The crystal structure is stabilized by inter­molecular O—H⋯O and O—H⋯N hydrogen bonds. International Union of Crystallography 2008-07-09 /pmc/articles/PMC2961931/ /pubmed/21203002 http://dx.doi.org/10.1107/S1600536808020503 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Xiu-Zhi
Wu, Bao-Zhen
Qu, Zhi-Rong
Poly[diaqua-1κ(2) O-bis[μ(3)-2-(1H-tetra­zol-5-yl)benzoato(2−)]dicadmium(II)]
title Poly[diaqua-1κ(2) O-bis[μ(3)-2-(1H-tetra­zol-5-yl)benzoato(2−)]dicadmium(II)]
title_full Poly[diaqua-1κ(2) O-bis[μ(3)-2-(1H-tetra­zol-5-yl)benzoato(2−)]dicadmium(II)]
title_fullStr Poly[diaqua-1κ(2) O-bis[μ(3)-2-(1H-tetra­zol-5-yl)benzoato(2−)]dicadmium(II)]
title_full_unstemmed Poly[diaqua-1κ(2) O-bis[μ(3)-2-(1H-tetra­zol-5-yl)benzoato(2−)]dicadmium(II)]
title_short Poly[diaqua-1κ(2) O-bis[μ(3)-2-(1H-tetra­zol-5-yl)benzoato(2−)]dicadmium(II)]
title_sort poly[diaqua-1κ(2) o-bis[μ(3)-2-(1h-tetra­zol-5-yl)benzoato(2−)]dicadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961931/
https://www.ncbi.nlm.nih.gov/pubmed/21203002
http://dx.doi.org/10.1107/S1600536808020503
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AT wubaozhen polydiaqua1k2obism321htetrazol5ylbenzoato2dicadmiumii
AT quzhirong polydiaqua1k2obism321htetrazol5ylbenzoato2dicadmiumii