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Poly[diaqua-1κ(2) O-bis[μ(3)-2-(1H-tetrazol-5-yl)benzoato(2−)]dicadmium(II)]
The title compound, [Cd(2)(C(8)H(4)N(4)O(2))(2)(H(2)O)(2)](n), is a coordination polymer prepared by the hydrothermal reaction of cadmium(II) chloride and 2-(1H-tetrazol-5-yl)benzoic acid. Two types of coordinated cadmium cations exist in the structure. One is located on a twofold axis and is coor...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961931/ https://www.ncbi.nlm.nih.gov/pubmed/21203002 http://dx.doi.org/10.1107/S1600536808020503 |
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author | Li, Xiu-Zhi Wu, Bao-Zhen Qu, Zhi-Rong |
author_facet | Li, Xiu-Zhi Wu, Bao-Zhen Qu, Zhi-Rong |
author_sort | Li, Xiu-Zhi |
collection | PubMed |
description | The title compound, [Cd(2)(C(8)H(4)N(4)O(2))(2)(H(2)O)(2)](n), is a coordination polymer prepared by the hydrothermal reaction of cadmium(II) chloride and 2-(1H-tetrazol-5-yl)benzoic acid. Two types of coordinated cadmium cations exist in the structure. One is located on a twofold axis and is coordinated by four O and two N atoms from four symmetry-related ligands, forming a trigonal-prismatic coordination polyhedron. The other is located on an inversion center and is octahedrally coordinated by two N and two O atoms from two ligands in equatorial sites, and two water molecules in axial sites. The organic ligand bridges three Cd atoms, through a carboxylate group and two N atoms of the tetrazolate unit. This mode of coordination results in a two-dimensional framework. The crystal structure is stabilized by intermolecular O—H⋯O and O—H⋯N hydrogen bonds. |
format | Text |
id | pubmed-2961931 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29619312010-12-30 Poly[diaqua-1κ(2) O-bis[μ(3)-2-(1H-tetrazol-5-yl)benzoato(2−)]dicadmium(II)] Li, Xiu-Zhi Wu, Bao-Zhen Qu, Zhi-Rong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(2)(C(8)H(4)N(4)O(2))(2)(H(2)O)(2)](n), is a coordination polymer prepared by the hydrothermal reaction of cadmium(II) chloride and 2-(1H-tetrazol-5-yl)benzoic acid. Two types of coordinated cadmium cations exist in the structure. One is located on a twofold axis and is coordinated by four O and two N atoms from four symmetry-related ligands, forming a trigonal-prismatic coordination polyhedron. The other is located on an inversion center and is octahedrally coordinated by two N and two O atoms from two ligands in equatorial sites, and two water molecules in axial sites. The organic ligand bridges three Cd atoms, through a carboxylate group and two N atoms of the tetrazolate unit. This mode of coordination results in a two-dimensional framework. The crystal structure is stabilized by intermolecular O—H⋯O and O—H⋯N hydrogen bonds. International Union of Crystallography 2008-07-09 /pmc/articles/PMC2961931/ /pubmed/21203002 http://dx.doi.org/10.1107/S1600536808020503 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Xiu-Zhi Wu, Bao-Zhen Qu, Zhi-Rong Poly[diaqua-1κ(2) O-bis[μ(3)-2-(1H-tetrazol-5-yl)benzoato(2−)]dicadmium(II)] |
title | Poly[diaqua-1κ(2)
O-bis[μ(3)-2-(1H-tetrazol-5-yl)benzoato(2−)]dicadmium(II)] |
title_full | Poly[diaqua-1κ(2)
O-bis[μ(3)-2-(1H-tetrazol-5-yl)benzoato(2−)]dicadmium(II)] |
title_fullStr | Poly[diaqua-1κ(2)
O-bis[μ(3)-2-(1H-tetrazol-5-yl)benzoato(2−)]dicadmium(II)] |
title_full_unstemmed | Poly[diaqua-1κ(2)
O-bis[μ(3)-2-(1H-tetrazol-5-yl)benzoato(2−)]dicadmium(II)] |
title_short | Poly[diaqua-1κ(2)
O-bis[μ(3)-2-(1H-tetrazol-5-yl)benzoato(2−)]dicadmium(II)] |
title_sort | poly[diaqua-1κ(2)
o-bis[μ(3)-2-(1h-tetrazol-5-yl)benzoato(2−)]dicadmium(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961931/ https://www.ncbi.nlm.nih.gov/pubmed/21203002 http://dx.doi.org/10.1107/S1600536808020503 |
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