(Benzoato-κ(2) O,O′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate

The Ni atom in the title salt, [Ni(C(7)H(5)O(2))(C(16)H(36)N(4))]ClO(4)·H(2)O, is in a six-coordinate octa­hedral geometry. The metal atom is chelated by the carboxyl­ate group, and the macrocyclic ligand adopts a folded configuration. The cation, anion and water mol­ecules engage in hydrogen bondin...

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Detalles Bibliográficos
Autores principales: Ou, Guang-Chuan, Zhang, Min, Yuan, Xian-You
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961933/
https://www.ncbi.nlm.nih.gov/pubmed/21203004
http://dx.doi.org/10.1107/S1600536808020564
Descripción
Sumario:The Ni atom in the title salt, [Ni(C(7)H(5)O(2))(C(16)H(36)N(4))]ClO(4)·H(2)O, is in a six-coordinate octa­hedral geometry. The metal atom is chelated by the carboxyl­ate group, and the macrocyclic ligand adopts a folded configuration. The cation, anion and water mol­ecules engage in hydrogen bonding to form a layer structure.

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