(Benzoato-κ(2) O,O′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate

The Ni atom in the title salt, [Ni(C(7)H(5)O(2))(C(16)H(36)N(4))]ClO(4)·H(2)O, is in a six-coordinate octa­hedral geometry. The metal atom is chelated by the carboxyl­ate group, and the macrocyclic ligand adopts a folded configuration. The cation, anion and water mol­ecules engage in hydrogen bondin...

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Detalles Bibliográficos
Autores principales: Ou, Guang-Chuan, Zhang, Min, Yuan, Xian-You
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961933/
https://www.ncbi.nlm.nih.gov/pubmed/21203004
http://dx.doi.org/10.1107/S1600536808020564
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author Ou, Guang-Chuan
Zhang, Min
Yuan, Xian-You
author_facet Ou, Guang-Chuan
Zhang, Min
Yuan, Xian-You
author_sort Ou, Guang-Chuan
collection PubMed
description The Ni atom in the title salt, [Ni(C(7)H(5)O(2))(C(16)H(36)N(4))]ClO(4)·H(2)O, is in a six-coordinate octa­hedral geometry. The metal atom is chelated by the carboxyl­ate group, and the macrocyclic ligand adopts a folded configuration. The cation, anion and water mol­ecules engage in hydrogen bonding to form a layer structure.
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spelling pubmed-29619332010-12-30 (Benzoato-κ(2) O,O′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate Ou, Guang-Chuan Zhang, Min Yuan, Xian-You Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ni atom in the title salt, [Ni(C(7)H(5)O(2))(C(16)H(36)N(4))]ClO(4)·H(2)O, is in a six-coordinate octa­hedral geometry. The metal atom is chelated by the carboxyl­ate group, and the macrocyclic ligand adopts a folded configuration. The cation, anion and water mol­ecules engage in hydrogen bonding to form a layer structure. International Union of Crystallography 2008-07-09 /pmc/articles/PMC2961933/ /pubmed/21203004 http://dx.doi.org/10.1107/S1600536808020564 Text en © Ou et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ou, Guang-Chuan
Zhang, Min
Yuan, Xian-You
(Benzoato-κ(2) O,O′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate
title (Benzoato-κ(2) O,O′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate
title_full (Benzoato-κ(2) O,O′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate
title_fullStr (Benzoato-κ(2) O,O′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate
title_full_unstemmed (Benzoato-κ(2) O,O′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate
title_short (Benzoato-κ(2) O,O′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate
title_sort (benzoato-κ(2) o,o′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) n,n′,n′′,n′′′)nickel(ii) perchlorate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961933/
https://www.ncbi.nlm.nih.gov/pubmed/21203004
http://dx.doi.org/10.1107/S1600536808020564
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AT zhangmin benzoatok2oo557121214hexamethyl14811tetraazacyclotetradecanek4nnnnnickeliiperchloratemonohydrate
AT yuanxianyou benzoatok2oo557121214hexamethyl14811tetraazacyclotetradecanek4nnnnnickeliiperchloratemonohydrate

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