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catena-Poly[copper(II)-bis(μ-2,4-dichloro-6-formylphenolato)-κ(3) O,O′:Cl (4);κ(3) Cl (4):O,O′]
In the title compound, [Cu(C(7)H(3)Cl(2)O(2))(2)](n), the Cu(II) atom lies on a centre of inversion and adopts a [4+2] coordination mode, with two long axial Cu—Cl coordinative bonds complementing four Cu—O bonds from two 2,4-dichloro-6-formylphenolate ligands in a distorted square plane. π–π stack...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961934/ https://www.ncbi.nlm.nih.gov/pubmed/21203005 http://dx.doi.org/10.1107/S1600536808020424 |
Sumario: | In the title compound, [Cu(C(7)H(3)Cl(2)O(2))(2)](n), the Cu(II) atom lies on a centre of inversion and adopts a [4+2] coordination mode, with two long axial Cu—Cl coordinative bonds complementing four Cu—O bonds from two 2,4-dichloro-6-formylphenolate ligands in a distorted square plane. π–π stacking interactions are also formed between neighbouring aromatic rings, with a centroid–centroid separation of 3.624 (2) Å. |
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