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catena-Poly[copper(II)-bis(μ-2,4-dichloro-6-formylphenolato)-κ(3) O,O′:Cl (4);κ(3) Cl (4):O,O′]
In the title compound, [Cu(C(7)H(3)Cl(2)O(2))(2)](n), the Cu(II) atom lies on a centre of inversion and adopts a [4+2] coordination mode, with two long axial Cu—Cl coordinative bonds complementing four Cu—O bonds from two 2,4-dichloro-6-formylphenolate ligands in a distorted square plane. π–π stack...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961934/ https://www.ncbi.nlm.nih.gov/pubmed/21203005 http://dx.doi.org/10.1107/S1600536808020424 |
| _version_ | 1782189100981288960 |
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| author | Fan, Ying You, Wei Liu, Jian-Lan Qian, Hui-Fen Huang, Wei |
| author_facet | Fan, Ying You, Wei Liu, Jian-Lan Qian, Hui-Fen Huang, Wei |
| author_sort | Fan, Ying |
| collection | PubMed |
| description | In the title compound, [Cu(C(7)H(3)Cl(2)O(2))(2)](n), the Cu(II) atom lies on a centre of inversion and adopts a [4+2] coordination mode, with two long axial Cu—Cl coordinative bonds complementing four Cu—O bonds from two 2,4-dichloro-6-formylphenolate ligands in a distorted square plane. π–π stacking interactions are also formed between neighbouring aromatic rings, with a centroid–centroid separation of 3.624 (2) Å. |
| format | Text |
| id | pubmed-2961934 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29619342010-12-30 catena-Poly[copper(II)-bis(μ-2,4-dichloro-6-formylphenolato)-κ(3) O,O′:Cl (4);κ(3) Cl (4):O,O′] Fan, Ying You, Wei Liu, Jian-Lan Qian, Hui-Fen Huang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(7)H(3)Cl(2)O(2))(2)](n), the Cu(II) atom lies on a centre of inversion and adopts a [4+2] coordination mode, with two long axial Cu—Cl coordinative bonds complementing four Cu—O bonds from two 2,4-dichloro-6-formylphenolate ligands in a distorted square plane. π–π stacking interactions are also formed between neighbouring aromatic rings, with a centroid–centroid separation of 3.624 (2) Å. International Union of Crystallography 2008-07-09 /pmc/articles/PMC2961934/ /pubmed/21203005 http://dx.doi.org/10.1107/S1600536808020424 Text en © Fan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Fan, Ying You, Wei Liu, Jian-Lan Qian, Hui-Fen Huang, Wei catena-Poly[copper(II)-bis(μ-2,4-dichloro-6-formylphenolato)-κ(3) O,O′:Cl (4);κ(3) Cl (4):O,O′] |
| title |
catena-Poly[copper(II)-bis(μ-2,4-dichloro-6-formylphenolato)-κ(3)
O,O′:Cl
(4);κ(3)
Cl
(4):O,O′] |
| title_full |
catena-Poly[copper(II)-bis(μ-2,4-dichloro-6-formylphenolato)-κ(3)
O,O′:Cl
(4);κ(3)
Cl
(4):O,O′] |
| title_fullStr |
catena-Poly[copper(II)-bis(μ-2,4-dichloro-6-formylphenolato)-κ(3)
O,O′:Cl
(4);κ(3)
Cl
(4):O,O′] |
| title_full_unstemmed |
catena-Poly[copper(II)-bis(μ-2,4-dichloro-6-formylphenolato)-κ(3)
O,O′:Cl
(4);κ(3)
Cl
(4):O,O′] |
| title_short |
catena-Poly[copper(II)-bis(μ-2,4-dichloro-6-formylphenolato)-κ(3)
O,O′:Cl
(4);κ(3)
Cl
(4):O,O′] |
| title_sort | catena-poly[copper(ii)-bis(μ-2,4-dichloro-6-formylphenolato)-κ(3)
o,o′:cl
(4);κ(3)
cl
(4):o,o′] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961934/ https://www.ncbi.nlm.nih.gov/pubmed/21203005 http://dx.doi.org/10.1107/S1600536808020424 |
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