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Dichloridobis(3,5-dimethyl-1H-pyrazol-4-amine-κN (2))cobalt(II)
In the title compound, [CoCl(2)(C(5)H(9)N(3))(2)], the Co(II) atom adopts a slightly distorted tetrahedral coordination geometry provided by two chloride anions and two N atoms from the organic ligands. The dihedral angle between the pyrazole rings is 85.91 (10)°. In the crystal structure, molecul...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961935/ https://www.ncbi.nlm.nih.gov/pubmed/21203006 http://dx.doi.org/10.1107/S1600536808020461 |
| _version_ | 1782189101215121408 |
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| author | Cai, Xing-Wei Zhao, Yu-Yuan Han, Guang-Fan |
| author_facet | Cai, Xing-Wei Zhao, Yu-Yuan Han, Guang-Fan |
| author_sort | Cai, Xing-Wei |
| collection | PubMed |
| description | In the title compound, [CoCl(2)(C(5)H(9)N(3))(2)], the Co(II) atom adopts a slightly distorted tetrahedral coordination geometry provided by two chloride anions and two N atoms from the organic ligands. The dihedral angle between the pyrazole rings is 85.91 (10)°. In the crystal structure, molecules are linked into a three-dimensional network by intermolecular N—H⋯N and N—H⋯Cl hydrogen-bonding interactions. |
| format | Text |
| id | pubmed-2961935 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29619352010-12-30 Dichloridobis(3,5-dimethyl-1H-pyrazol-4-amine-κN (2))cobalt(II) Cai, Xing-Wei Zhao, Yu-Yuan Han, Guang-Fan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoCl(2)(C(5)H(9)N(3))(2)], the Co(II) atom adopts a slightly distorted tetrahedral coordination geometry provided by two chloride anions and two N atoms from the organic ligands. The dihedral angle between the pyrazole rings is 85.91 (10)°. In the crystal structure, molecules are linked into a three-dimensional network by intermolecular N—H⋯N and N—H⋯Cl hydrogen-bonding interactions. International Union of Crystallography 2008-07-09 /pmc/articles/PMC2961935/ /pubmed/21203006 http://dx.doi.org/10.1107/S1600536808020461 Text en © Cai et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Cai, Xing-Wei Zhao, Yu-Yuan Han, Guang-Fan Dichloridobis(3,5-dimethyl-1H-pyrazol-4-amine-κN (2))cobalt(II) |
| title | Dichloridobis(3,5-dimethyl-1H-pyrazol-4-amine-κN
(2))cobalt(II) |
| title_full | Dichloridobis(3,5-dimethyl-1H-pyrazol-4-amine-κN
(2))cobalt(II) |
| title_fullStr | Dichloridobis(3,5-dimethyl-1H-pyrazol-4-amine-κN
(2))cobalt(II) |
| title_full_unstemmed | Dichloridobis(3,5-dimethyl-1H-pyrazol-4-amine-κN
(2))cobalt(II) |
| title_short | Dichloridobis(3,5-dimethyl-1H-pyrazol-4-amine-κN
(2))cobalt(II) |
| title_sort | dichloridobis(3,5-dimethyl-1h-pyrazol-4-amine-κn
(2))cobalt(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961935/ https://www.ncbi.nlm.nih.gov/pubmed/21203006 http://dx.doi.org/10.1107/S1600536808020461 |
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