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Chlorido[6-phenyl-4-(p-tolyl)-2,2′-bipyridyl-κ(2) N,N′]platinum(II)
The asymmetric unit of the title compound, [Pt(C(23)H(17)N(2))Cl], contains two independent molecules with distinct dihedral angles between the central pyridyl and methylbenzene rings [7.77 (2) and 24.07 (2)°]. Short intermolecular distances [3.582 (6) and 3.600 (6) Å] between the outer pyridine a...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961937/ https://www.ncbi.nlm.nih.gov/pubmed/21203007 http://dx.doi.org/10.1107/S1600536808020473 |
| Sumario: | The asymmetric unit of the title compound, [Pt(C(23)H(17)N(2))Cl], contains two independent molecules with distinct dihedral angles between the central pyridyl and methylbenzene rings [7.77 (2) and 24.07 (2)°]. Short intermolecular distances [3.582 (6) and 3.600 (6) Å] between the outer pyridine and the PtNC(3) and PtN(2)C(2) rings, respectively, indicate the existence of π–π interactions, which link the molecules into stacks along the a axis. The crystal structure is further stabilized by weak C—H⋯π interactions. |
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