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Chlorido[6-phenyl-4-(p-tolyl)-2,2′-bipyridyl-κ(2) N,N′]platinum(II)
The asymmetric unit of the title compound, [Pt(C(23)H(17)N(2))Cl], contains two independent molecules with distinct dihedral angles between the central pyridyl and methylbenzene rings [7.77 (2) and 24.07 (2)°]. Short intermolecular distances [3.582 (6) and 3.600 (6) Å] between the outer pyridine a...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961937/ https://www.ncbi.nlm.nih.gov/pubmed/21203007 http://dx.doi.org/10.1107/S1600536808020473 |
| _version_ | 1782189101689077760 |
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| author | Lu, Hong Bo Lv, Guo Qiang Zuo, Jin Lin Yang, Jia Xiang |
| author_facet | Lu, Hong Bo Lv, Guo Qiang Zuo, Jin Lin Yang, Jia Xiang |
| author_sort | Lu, Hong Bo |
| collection | PubMed |
| description | The asymmetric unit of the title compound, [Pt(C(23)H(17)N(2))Cl], contains two independent molecules with distinct dihedral angles between the central pyridyl and methylbenzene rings [7.77 (2) and 24.07 (2)°]. Short intermolecular distances [3.582 (6) and 3.600 (6) Å] between the outer pyridine and the PtNC(3) and PtN(2)C(2) rings, respectively, indicate the existence of π–π interactions, which link the molecules into stacks along the a axis. The crystal structure is further stabilized by weak C—H⋯π interactions. |
| format | Text |
| id | pubmed-2961937 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29619372010-12-30 Chlorido[6-phenyl-4-(p-tolyl)-2,2′-bipyridyl-κ(2) N,N′]platinum(II) Lu, Hong Bo Lv, Guo Qiang Zuo, Jin Lin Yang, Jia Xiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Pt(C(23)H(17)N(2))Cl], contains two independent molecules with distinct dihedral angles between the central pyridyl and methylbenzene rings [7.77 (2) and 24.07 (2)°]. Short intermolecular distances [3.582 (6) and 3.600 (6) Å] between the outer pyridine and the PtNC(3) and PtN(2)C(2) rings, respectively, indicate the existence of π–π interactions, which link the molecules into stacks along the a axis. The crystal structure is further stabilized by weak C—H⋯π interactions. International Union of Crystallography 2008-07-09 /pmc/articles/PMC2961937/ /pubmed/21203007 http://dx.doi.org/10.1107/S1600536808020473 Text en © Lu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lu, Hong Bo Lv, Guo Qiang Zuo, Jin Lin Yang, Jia Xiang Chlorido[6-phenyl-4-(p-tolyl)-2,2′-bipyridyl-κ(2) N,N′]platinum(II) |
| title | Chlorido[6-phenyl-4-(p-tolyl)-2,2′-bipyridyl-κ(2)
N,N′]platinum(II) |
| title_full | Chlorido[6-phenyl-4-(p-tolyl)-2,2′-bipyridyl-κ(2)
N,N′]platinum(II) |
| title_fullStr | Chlorido[6-phenyl-4-(p-tolyl)-2,2′-bipyridyl-κ(2)
N,N′]platinum(II) |
| title_full_unstemmed | Chlorido[6-phenyl-4-(p-tolyl)-2,2′-bipyridyl-κ(2)
N,N′]platinum(II) |
| title_short | Chlorido[6-phenyl-4-(p-tolyl)-2,2′-bipyridyl-κ(2)
N,N′]platinum(II) |
| title_sort | chlorido[6-phenyl-4-(p-tolyl)-2,2′-bipyridyl-κ(2)
n,n′]platinum(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961937/ https://www.ncbi.nlm.nih.gov/pubmed/21203007 http://dx.doi.org/10.1107/S1600536808020473 |
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