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Tris(nitrato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)holmium(III)
In the title compound, [Ho(NO(3))(3)(C(12)H(8)N(2))(2)], the ten-coordinate Ho(III) ion is chelated by four N atoms from two phenanthroline (phen) ligands and six O atoms from three bidentate nitrate groups. The environment around the Ho atom can be described as a distorted bicapped square antipris...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961938/ https://www.ncbi.nlm.nih.gov/pubmed/21203008 http://dx.doi.org/10.1107/S1600536808020655 |
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| author | Kusrini, Eny Saleh, Muhammad Idiris Kia, Reza Fun, Hoong-Kun |
| author_facet | Kusrini, Eny Saleh, Muhammad Idiris Kia, Reza Fun, Hoong-Kun |
| author_sort | Kusrini, Eny |
| collection | PubMed |
| description | In the title compound, [Ho(NO(3))(3)(C(12)H(8)N(2))(2)], the ten-coordinate Ho(III) ion is chelated by four N atoms from two phenanthroline (phen) ligands and six O atoms from three bidentate nitrate groups. The environment around the Ho atom can be described as a distorted bicapped square antiprism. Two phenanthroline ligands form a dihedral angle of 43.72 (13)°. Short intermolecular distances between the centroids of the six-membered rings [3.6887 (14)–3.8374 (16) Å] indicate the existence of π–π interactions, which link the molecules into stacks extended in the [10[Image: see text]] direction. The crystal packing is further stabilized by weak intermolecular C—H⋯O hydrogen bonds. |
| format | Text |
| id | pubmed-2961938 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29619382010-12-30 Tris(nitrato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)holmium(III) Kusrini, Eny Saleh, Muhammad Idiris Kia, Reza Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ho(NO(3))(3)(C(12)H(8)N(2))(2)], the ten-coordinate Ho(III) ion is chelated by four N atoms from two phenanthroline (phen) ligands and six O atoms from three bidentate nitrate groups. The environment around the Ho atom can be described as a distorted bicapped square antiprism. Two phenanthroline ligands form a dihedral angle of 43.72 (13)°. Short intermolecular distances between the centroids of the six-membered rings [3.6887 (14)–3.8374 (16) Å] indicate the existence of π–π interactions, which link the molecules into stacks extended in the [10[Image: see text]] direction. The crystal packing is further stabilized by weak intermolecular C—H⋯O hydrogen bonds. International Union of Crystallography 2008-07-09 /pmc/articles/PMC2961938/ /pubmed/21203008 http://dx.doi.org/10.1107/S1600536808020655 Text en © Kusrini et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kusrini, Eny Saleh, Muhammad Idiris Kia, Reza Fun, Hoong-Kun Tris(nitrato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)holmium(III) |
| title | Tris(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)holmium(III) |
| title_full | Tris(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)holmium(III) |
| title_fullStr | Tris(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)holmium(III) |
| title_full_unstemmed | Tris(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)holmium(III) |
| title_short | Tris(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)holmium(III) |
| title_sort | tris(nitrato-κ(2)
o,o′)bis(1,10-phenanthroline-κ(2)
n,n′)holmium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961938/ https://www.ncbi.nlm.nih.gov/pubmed/21203008 http://dx.doi.org/10.1107/S1600536808020655 |
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