Bis(nitrato-κO)[(S)-2-(pyrrolidin-2-yl)-1H-benzimidazole]cadmium(II)

The title compound, [Cd(NO(3))(2)(C(11)H(13)N(3))(2)], was synthesized by hydro­thermal reaction of Cd(NO(3))(2) and S-2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole. The Cd atom lies on an inversion centre. The distorted octa­hedral Cd environment contains two planar trans-related N,N-chelating S-2-(pyrr...

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Detalles Bibliográficos
Autores principales: Dai, Wei, Fu, Da-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961940/
https://www.ncbi.nlm.nih.gov/pubmed/21203010
http://dx.doi.org/10.1107/S1600536808006454
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author Dai, Wei
Fu, Da-Wei
author_facet Dai, Wei
Fu, Da-Wei
author_sort Dai, Wei
collection PubMed
description The title compound, [Cd(NO(3))(2)(C(11)H(13)N(3))(2)], was synthesized by hydro­thermal reaction of Cd(NO(3))(2) and S-2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole. The Cd atom lies on an inversion centre. The distorted octa­hedral Cd environment contains two planar trans-related N,N-chelating S-2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole ligands in one plane and two monodentate nitrate ligands. N—H⋯O hydrogen bonds involving a nitrate O atom build up an infinite chain parallel to the a axis.
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spelling pubmed-29619402010-12-30 Bis(nitrato-κO)[(S)-2-(pyrrolidin-2-yl)-1H-benzimidazole]cadmium(II) Dai, Wei Fu, Da-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(NO(3))(2)(C(11)H(13)N(3))(2)], was synthesized by hydro­thermal reaction of Cd(NO(3))(2) and S-2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole. The Cd atom lies on an inversion centre. The distorted octa­hedral Cd environment contains two planar trans-related N,N-chelating S-2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole ligands in one plane and two monodentate nitrate ligands. N—H⋯O hydrogen bonds involving a nitrate O atom build up an infinite chain parallel to the a axis. International Union of Crystallography 2008-07-09 /pmc/articles/PMC2961940/ /pubmed/21203010 http://dx.doi.org/10.1107/S1600536808006454 Text en © Dai and Fu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dai, Wei
Fu, Da-Wei
Bis(nitrato-κO)[(S)-2-(pyrrolidin-2-yl)-1H-benzimidazole]cadmium(II)
title Bis(nitrato-κO)[(S)-2-(pyrrolidin-2-yl)-1H-benzimidazole]cadmium(II)
title_full Bis(nitrato-κO)[(S)-2-(pyrrolidin-2-yl)-1H-benzimidazole]cadmium(II)
title_fullStr Bis(nitrato-κO)[(S)-2-(pyrrolidin-2-yl)-1H-benzimidazole]cadmium(II)
title_full_unstemmed Bis(nitrato-κO)[(S)-2-(pyrrolidin-2-yl)-1H-benzimidazole]cadmium(II)
title_short Bis(nitrato-κO)[(S)-2-(pyrrolidin-2-yl)-1H-benzimidazole]cadmium(II)
title_sort bis(nitrato-κo)[(s)-2-(pyrrolidin-2-yl)-1h-benzimidazole]cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961940/
https://www.ncbi.nlm.nih.gov/pubmed/21203010
http://dx.doi.org/10.1107/S1600536808006454
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