Bis(μ-N-benzyl-N-methyl­dithio­carbamato)-1:2κ(3) S,S′:S′;1:2κ(3) S:S,S′-bis­[bis­(N-benzyl-N-methyl­dithio­carbamato-κ(2) S,S′)thallium(III)]

The molecule of the dinuclear title compound, [Tl(2)(C(9)H(10)NS(2))(6)], possesses a crystallographically imposed centre of symmetry. Each Tl(III) atom is seven-coordinated by S atoms of four different dithio­carbamate anions in a distorted penta­gonal-bipyramidal coordination geometry. The crystal...

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Detalles Bibliográficos
Autores principales: Rizzoli, Corrado, Ramalingam, Kuppukkannu, Alexander, Nagarajan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961943/
https://www.ncbi.nlm.nih.gov/pubmed/21203013
http://dx.doi.org/10.1107/S1600536808021004
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author Rizzoli, Corrado
Ramalingam, Kuppukkannu
Alexander, Nagarajan
author_facet Rizzoli, Corrado
Ramalingam, Kuppukkannu
Alexander, Nagarajan
author_sort Rizzoli, Corrado
collection PubMed
description The molecule of the dinuclear title compound, [Tl(2)(C(9)H(10)NS(2))(6)], possesses a crystallographically imposed centre of symmetry. Each Tl(III) atom is seven-coordinated by S atoms of four different dithio­carbamate anions in a distorted penta­gonal-bipyramidal coordination geometry. The crystal structure is stabilized by a C—H⋯S hydrogen-bond inter­action linking complex mol­ecules into chains running parallel to the b axis. Intramolecular C—H⋯S hydrogen bonds are also present.
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spelling pubmed-29619432010-12-30 Bis(μ-N-benzyl-N-methyl­dithio­carbamato)-1:2κ(3) S,S′:S′;1:2κ(3) S:S,S′-bis­[bis­(N-benzyl-N-methyl­dithio­carbamato-κ(2) S,S′)thallium(III)] Rizzoli, Corrado Ramalingam, Kuppukkannu Alexander, Nagarajan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The molecule of the dinuclear title compound, [Tl(2)(C(9)H(10)NS(2))(6)], possesses a crystallographically imposed centre of symmetry. Each Tl(III) atom is seven-coordinated by S atoms of four different dithio­carbamate anions in a distorted penta­gonal-bipyramidal coordination geometry. The crystal structure is stabilized by a C—H⋯S hydrogen-bond inter­action linking complex mol­ecules into chains running parallel to the b axis. Intramolecular C—H⋯S hydrogen bonds are also present. International Union of Crystallography 2008-07-12 /pmc/articles/PMC2961943/ /pubmed/21203013 http://dx.doi.org/10.1107/S1600536808021004 Text en © Rizzoli et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rizzoli, Corrado
Ramalingam, Kuppukkannu
Alexander, Nagarajan
Bis(μ-N-benzyl-N-methyl­dithio­carbamato)-1:2κ(3) S,S′:S′;1:2κ(3) S:S,S′-bis­[bis­(N-benzyl-N-methyl­dithio­carbamato-κ(2) S,S′)thallium(III)]
title Bis(μ-N-benzyl-N-methyl­dithio­carbamato)-1:2κ(3) S,S′:S′;1:2κ(3) S:S,S′-bis­[bis­(N-benzyl-N-methyl­dithio­carbamato-κ(2) S,S′)thallium(III)]
title_full Bis(μ-N-benzyl-N-methyl­dithio­carbamato)-1:2κ(3) S,S′:S′;1:2κ(3) S:S,S′-bis­[bis­(N-benzyl-N-methyl­dithio­carbamato-κ(2) S,S′)thallium(III)]
title_fullStr Bis(μ-N-benzyl-N-methyl­dithio­carbamato)-1:2κ(3) S,S′:S′;1:2κ(3) S:S,S′-bis­[bis­(N-benzyl-N-methyl­dithio­carbamato-κ(2) S,S′)thallium(III)]
title_full_unstemmed Bis(μ-N-benzyl-N-methyl­dithio­carbamato)-1:2κ(3) S,S′:S′;1:2κ(3) S:S,S′-bis­[bis­(N-benzyl-N-methyl­dithio­carbamato-κ(2) S,S′)thallium(III)]
title_short Bis(μ-N-benzyl-N-methyl­dithio­carbamato)-1:2κ(3) S,S′:S′;1:2κ(3) S:S,S′-bis­[bis­(N-benzyl-N-methyl­dithio­carbamato-κ(2) S,S′)thallium(III)]
title_sort bis(μ-n-benzyl-n-methyl­dithio­carbamato)-1:2κ(3) s,s′:s′;1:2κ(3) s:s,s′-bis­[bis­(n-benzyl-n-methyl­dithio­carbamato-κ(2) s,s′)thallium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961943/
https://www.ncbi.nlm.nih.gov/pubmed/21203013
http://dx.doi.org/10.1107/S1600536808021004
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