A new monoclinic polymorph of dichlorido­tetra­kis(dimethyl sulfoxide)­ruthenium(II)

The title compound, cis,fac-dichloridotetra­kis(dimethyl sulfoxide)-κ(3) S,κO-ruthenium(II), [RuCl(2)(C(2)H(6)OS)(4)], was obtained from newly synthesized ruthenium complexes of 3-amino-2-chloro­pyridine. The Ru atom has a distorted octa­hedral coordination with two cis-oriented chloride ligands and...

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Autores principales: Georgieva, Gergana, Gencheva, Galina, Shivachev, Boris Lubomirov, Nikolova, Rosica Petrova
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961945/
https://www.ncbi.nlm.nih.gov/pubmed/21203015
http://dx.doi.org/10.1107/S160053680801996X
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author Georgieva, Gergana
Gencheva, Galina
Shivachev, Boris Lubomirov
Nikolova, Rosica Petrova
author_facet Georgieva, Gergana
Gencheva, Galina
Shivachev, Boris Lubomirov
Nikolova, Rosica Petrova
author_sort Georgieva, Gergana
collection PubMed
description The title compound, cis,fac-dichloridotetra­kis(dimethyl sulfoxide)-κ(3) S,κO-ruthenium(II), [RuCl(2)(C(2)H(6)OS)(4)], was obtained from newly synthesized ruthenium complexes of 3-amino-2-chloro­pyridine. The Ru atom has a distorted octa­hedral coordination with two cis-oriented chloride ligands and four dimethyl sulfoxide ligands. Three of the sulfoxide ligands are S-bonded in a fac configuration, while the fourth is O-bonded. The title compound represents a new, and fourth, polymorph of the complex. Two other monoclinic forms and an ortho­rhom­bic modification have been reported previously.
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spelling pubmed-29619452010-12-30 A new monoclinic polymorph of dichlorido­tetra­kis(dimethyl sulfoxide)­ruthenium(II) Georgieva, Gergana Gencheva, Galina Shivachev, Boris Lubomirov Nikolova, Rosica Petrova Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, cis,fac-dichloridotetra­kis(dimethyl sulfoxide)-κ(3) S,κO-ruthenium(II), [RuCl(2)(C(2)H(6)OS)(4)], was obtained from newly synthesized ruthenium complexes of 3-amino-2-chloro­pyridine. The Ru atom has a distorted octa­hedral coordination with two cis-oriented chloride ligands and four dimethyl sulfoxide ligands. Three of the sulfoxide ligands are S-bonded in a fac configuration, while the fourth is O-bonded. The title compound represents a new, and fourth, polymorph of the complex. Two other monoclinic forms and an ortho­rhom­bic modification have been reported previously. International Union of Crystallography 2008-07-12 /pmc/articles/PMC2961945/ /pubmed/21203015 http://dx.doi.org/10.1107/S160053680801996X Text en © Georgieva et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Georgieva, Gergana
Gencheva, Galina
Shivachev, Boris Lubomirov
Nikolova, Rosica Petrova
A new monoclinic polymorph of dichlorido­tetra­kis(dimethyl sulfoxide)­ruthenium(II)
title A new monoclinic polymorph of dichlorido­tetra­kis(dimethyl sulfoxide)­ruthenium(II)
title_full A new monoclinic polymorph of dichlorido­tetra­kis(dimethyl sulfoxide)­ruthenium(II)
title_fullStr A new monoclinic polymorph of dichlorido­tetra­kis(dimethyl sulfoxide)­ruthenium(II)
title_full_unstemmed A new monoclinic polymorph of dichlorido­tetra­kis(dimethyl sulfoxide)­ruthenium(II)
title_short A new monoclinic polymorph of dichlorido­tetra­kis(dimethyl sulfoxide)­ruthenium(II)
title_sort new monoclinic polymorph of dichlorido­tetra­kis(dimethyl sulfoxide)­ruthenium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961945/
https://www.ncbi.nlm.nih.gov/pubmed/21203015
http://dx.doi.org/10.1107/S160053680801996X
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