Hexaaqua­copper(II) dichloride bis­(hexa­methyl­enetetra­mine) tetra­hydrate

The title compound, [Cu(H(2)O)(6)]Cl(2)·2C(6)H(12)N(4)·4H(2)O, was prepared under mild hydro­thermal conditions. The asymmetric unit consists of one half of the [Cu(H(2)O)(6)](2+) cation, a hexa­methyl­enetetra­mine mol­ecule, two solvent water mol­ecules and a chloride ion. The formula unit is gene...

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Detalles Bibliográficos
Autores principales: Li, Zhan Lin, Yao, Xin Jian, Wu, Wen, Xuan, Ya Wen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961946/
https://www.ncbi.nlm.nih.gov/pubmed/21203016
http://dx.doi.org/10.1107/S1600536808020916
Descripción
Sumario:The title compound, [Cu(H(2)O)(6)]Cl(2)·2C(6)H(12)N(4)·4H(2)O, was prepared under mild hydro­thermal conditions. The asymmetric unit consists of one half of the [Cu(H(2)O)(6)](2+) cation, a hexa­methyl­enetetra­mine mol­ecule, two solvent water mol­ecules and a chloride ion. The formula unit is generated by crystallographic inversion symmetry. The Cu atom lies on a crystallographic inversion centre. It is in a slightly distorted octa­hedral coordination environment. In the crystal structure, inter­molecular O—H⋯O, O—H⋯N and O—H⋯Cl hydrogen bonds link the components into a three-dimensional network.

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