Hexaaqua­copper(II) dichloride bis­(hexa­methyl­enetetra­mine) tetra­hydrate

The title compound, [Cu(H(2)O)(6)]Cl(2)·2C(6)H(12)N(4)·4H(2)O, was prepared under mild hydro­thermal conditions. The asymmetric unit consists of one half of the [Cu(H(2)O)(6)](2+) cation, a hexa­methyl­enetetra­mine mol­ecule, two solvent water mol­ecules and a chloride ion. The formula unit is gene...

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Detalles Bibliográficos
Autores principales: Li, Zhan Lin, Yao, Xin Jian, Wu, Wen, Xuan, Ya Wen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961946/
https://www.ncbi.nlm.nih.gov/pubmed/21203016
http://dx.doi.org/10.1107/S1600536808020916
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author Li, Zhan Lin
Yao, Xin Jian
Wu, Wen
Xuan, Ya Wen
author_facet Li, Zhan Lin
Yao, Xin Jian
Wu, Wen
Xuan, Ya Wen
author_sort Li, Zhan Lin
collection PubMed
description The title compound, [Cu(H(2)O)(6)]Cl(2)·2C(6)H(12)N(4)·4H(2)O, was prepared under mild hydro­thermal conditions. The asymmetric unit consists of one half of the [Cu(H(2)O)(6)](2+) cation, a hexa­methyl­enetetra­mine mol­ecule, two solvent water mol­ecules and a chloride ion. The formula unit is generated by crystallographic inversion symmetry. The Cu atom lies on a crystallographic inversion centre. It is in a slightly distorted octa­hedral coordination environment. In the crystal structure, inter­molecular O—H⋯O, O—H⋯N and O—H⋯Cl hydrogen bonds link the components into a three-dimensional network.
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spelling pubmed-29619462010-12-30 Hexaaqua­copper(II) dichloride bis­(hexa­methyl­enetetra­mine) tetra­hydrate Li, Zhan Lin Yao, Xin Jian Wu, Wen Xuan, Ya Wen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(H(2)O)(6)]Cl(2)·2C(6)H(12)N(4)·4H(2)O, was prepared under mild hydro­thermal conditions. The asymmetric unit consists of one half of the [Cu(H(2)O)(6)](2+) cation, a hexa­methyl­enetetra­mine mol­ecule, two solvent water mol­ecules and a chloride ion. The formula unit is generated by crystallographic inversion symmetry. The Cu atom lies on a crystallographic inversion centre. It is in a slightly distorted octa­hedral coordination environment. In the crystal structure, inter­molecular O—H⋯O, O—H⋯N and O—H⋯Cl hydrogen bonds link the components into a three-dimensional network. International Union of Crystallography 2008-07-12 /pmc/articles/PMC2961946/ /pubmed/21203016 http://dx.doi.org/10.1107/S1600536808020916 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Zhan Lin
Yao, Xin Jian
Wu, Wen
Xuan, Ya Wen
Hexaaqua­copper(II) dichloride bis­(hexa­methyl­enetetra­mine) tetra­hydrate
title Hexaaqua­copper(II) dichloride bis­(hexa­methyl­enetetra­mine) tetra­hydrate
title_full Hexaaqua­copper(II) dichloride bis­(hexa­methyl­enetetra­mine) tetra­hydrate
title_fullStr Hexaaqua­copper(II) dichloride bis­(hexa­methyl­enetetra­mine) tetra­hydrate
title_full_unstemmed Hexaaqua­copper(II) dichloride bis­(hexa­methyl­enetetra­mine) tetra­hydrate
title_short Hexaaqua­copper(II) dichloride bis­(hexa­methyl­enetetra­mine) tetra­hydrate
title_sort hexaaqua­copper(ii) dichloride bis­(hexa­methyl­enetetra­mine) tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961946/
https://www.ncbi.nlm.nih.gov/pubmed/21203016
http://dx.doi.org/10.1107/S1600536808020916
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AT yaoxinjian hexaaquacopperiidichloridebishexamethylenetetraminetetrahydrate
AT wuwen hexaaquacopperiidichloridebishexamethylenetetraminetetrahydrate
AT xuanyawen hexaaquacopperiidichloridebishexamethylenetetraminetetrahydrate

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