catena-Poly[[dichloridocobalt(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′]

In the title compound, [CoCl(2)(C(13)H(14)N(2))](n), 1,3-bis­(4-pyrid­yl)propane (bpp) ligands bridge four-coordinate Co atoms, generating an extended one-dimensional zigzag chain. Both the Co and two Cl atoms in the tetrahedral coordination polyhedron lie on a mirror plane, while the bbp ligand is...

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Detalles Bibliográficos
Autores principales: Xu, Wei, Lin, Jian-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961947/
https://www.ncbi.nlm.nih.gov/pubmed/21203017
http://dx.doi.org/10.1107/S1600536808020862
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author Xu, Wei
Lin, Jian-Li
author_facet Xu, Wei
Lin, Jian-Li
author_sort Xu, Wei
collection PubMed
description In the title compound, [CoCl(2)(C(13)H(14)N(2))](n), 1,3-bis­(4-pyrid­yl)propane (bpp) ligands bridge four-coordinate Co atoms, generating an extended one-dimensional zigzag chain. Both the Co and two Cl atoms in the tetrahedral coordination polyhedron lie on a mirror plane, while the bbp ligand is bis­ected through the central C atom in the chain by a second mirror plane. There are some π–π stacking inter­ations in the crystal structure, with inter­planar distances of 3.449 Å, which are responsible for the supra­molecular assembly.
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spelling pubmed-29619472010-12-30 catena-Poly[[dichloridocobalt(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′] Xu, Wei Lin, Jian-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoCl(2)(C(13)H(14)N(2))](n), 1,3-bis­(4-pyrid­yl)propane (bpp) ligands bridge four-coordinate Co atoms, generating an extended one-dimensional zigzag chain. Both the Co and two Cl atoms in the tetrahedral coordination polyhedron lie on a mirror plane, while the bbp ligand is bis­ected through the central C atom in the chain by a second mirror plane. There are some π–π stacking inter­ations in the crystal structure, with inter­planar distances of 3.449 Å, which are responsible for the supra­molecular assembly. International Union of Crystallography 2008-07-12 /pmc/articles/PMC2961947/ /pubmed/21203017 http://dx.doi.org/10.1107/S1600536808020862 Text en © Xu and Lin 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Wei
Lin, Jian-Li
catena-Poly[[dichloridocobalt(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′]
title catena-Poly[[dichloridocobalt(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′]
title_full catena-Poly[[dichloridocobalt(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′]
title_fullStr catena-Poly[[dichloridocobalt(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′]
title_full_unstemmed catena-Poly[[dichloridocobalt(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′]
title_short catena-Poly[[dichloridocobalt(II)]-μ-1,3-di-4-pyridylpropane-κ(2) N:N′]
title_sort catena-poly[[dichloridocobalt(ii)]-μ-1,3-di-4-pyridylpropane-κ(2) n:n′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961947/
https://www.ncbi.nlm.nih.gov/pubmed/21203017
http://dx.doi.org/10.1107/S1600536808020862
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AT linjianli catenapolydichloridocobaltiim13di4pyridylpropanek2nn

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