Cargando…
catena-Poly[[diiodidomercury(II)]-μ-nicotine-κ(2) N:N′]
The title polymeric complex, [HgI(2)(C(10)H(14)N(2))](n), was prepared from a solution of nicotine, mercury(II) iodide and 4-cyanopyridine in dimethylformamide. Each nicotine molecule is bonded to two Hg atoms, one through the pyrrolidine N atom and the other through the pyridine N atom, forming...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961948/ https://www.ncbi.nlm.nih.gov/pubmed/21203018 http://dx.doi.org/10.1107/S1600536808020904 |
_version_ | 1782189104356655104 |
---|---|
author | Jiang, Zhengjing Tang, Guodong Lu, Lude |
author_facet | Jiang, Zhengjing Tang, Guodong Lu, Lude |
author_sort | Jiang, Zhengjing |
collection | PubMed |
description | The title polymeric complex, [HgI(2)(C(10)H(14)N(2))](n), was prepared from a solution of nicotine, mercury(II) iodide and 4-cyanopyridine in dimethylformamide. Each nicotine molecule is bonded to two Hg atoms, one through the pyrrolidine N atom and the other through the pyridine N atom, forming infinite zigzag polymeric chains. The coordination around mercury is completed by two iodide ligands, resulting in a distorted tetrahedral arrangement. |
format | Text |
id | pubmed-2961948 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29619482010-12-30 catena-Poly[[diiodidomercury(II)]-μ-nicotine-κ(2) N:N′] Jiang, Zhengjing Tang, Guodong Lu, Lude Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title polymeric complex, [HgI(2)(C(10)H(14)N(2))](n), was prepared from a solution of nicotine, mercury(II) iodide and 4-cyanopyridine in dimethylformamide. Each nicotine molecule is bonded to two Hg atoms, one through the pyrrolidine N atom and the other through the pyridine N atom, forming infinite zigzag polymeric chains. The coordination around mercury is completed by two iodide ligands, resulting in a distorted tetrahedral arrangement. International Union of Crystallography 2008-07-12 /pmc/articles/PMC2961948/ /pubmed/21203018 http://dx.doi.org/10.1107/S1600536808020904 Text en © Jiang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Jiang, Zhengjing Tang, Guodong Lu, Lude catena-Poly[[diiodidomercury(II)]-μ-nicotine-κ(2) N:N′] |
title |
catena-Poly[[diiodidomercury(II)]-μ-nicotine-κ(2)
N:N′] |
title_full |
catena-Poly[[diiodidomercury(II)]-μ-nicotine-κ(2)
N:N′] |
title_fullStr |
catena-Poly[[diiodidomercury(II)]-μ-nicotine-κ(2)
N:N′] |
title_full_unstemmed |
catena-Poly[[diiodidomercury(II)]-μ-nicotine-κ(2)
N:N′] |
title_short |
catena-Poly[[diiodidomercury(II)]-μ-nicotine-κ(2)
N:N′] |
title_sort | catena-poly[[diiodidomercury(ii)]-μ-nicotine-κ(2)
n:n′] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961948/ https://www.ncbi.nlm.nih.gov/pubmed/21203018 http://dx.doi.org/10.1107/S1600536808020904 |
work_keys_str_mv | AT jiangzhengjing catenapolydiiodidomercuryiimnicotinek2nn AT tangguodong catenapolydiiodidomercuryiimnicotinek2nn AT lulude catenapolydiiodidomercuryiimnicotinek2nn |