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3,3′-Bis(4-fluoro­benz­yl)-1,1′-ethyl­enediimidazolium tribromidocuprate(I)

The title compound, (C(22)H(22)F(2)N(4))[CuBr(3)], crystallizes with the cation situated on an inversion center and the anion on a twofold rotation axis along one Cu—Br bond. The two imidazole rings are in an anti configuration. The anion has a trigonal planar coordination geometry.

Detalles Bibliográficos
Autores principales: Lee, Hon Man, Lu, Chi-Ying, Cheng, Pi-Yun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961950/
https://www.ncbi.nlm.nih.gov/pubmed/21203020
http://dx.doi.org/10.1107/S1600536808021521
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author Lee, Hon Man
Lu, Chi-Ying
Cheng, Pi-Yun
author_facet Lee, Hon Man
Lu, Chi-Ying
Cheng, Pi-Yun
author_sort Lee, Hon Man
collection PubMed
description The title compound, (C(22)H(22)F(2)N(4))[CuBr(3)], crystallizes with the cation situated on an inversion center and the anion on a twofold rotation axis along one Cu—Br bond. The two imidazole rings are in an anti configuration. The anion has a trigonal planar coordination geometry.
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spelling pubmed-29619502010-12-30 3,3′-Bis(4-fluoro­benz­yl)-1,1′-ethyl­enediimidazolium tribromidocuprate(I) Lee, Hon Man Lu, Chi-Ying Cheng, Pi-Yun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(22)H(22)F(2)N(4))[CuBr(3)], crystallizes with the cation situated on an inversion center and the anion on a twofold rotation axis along one Cu—Br bond. The two imidazole rings are in an anti configuration. The anion has a trigonal planar coordination geometry. International Union of Crystallography 2008-07-16 /pmc/articles/PMC2961950/ /pubmed/21203020 http://dx.doi.org/10.1107/S1600536808021521 Text en © Lee et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lee, Hon Man
Lu, Chi-Ying
Cheng, Pi-Yun
3,3′-Bis(4-fluoro­benz­yl)-1,1′-ethyl­enediimidazolium tribromidocuprate(I)
title 3,3′-Bis(4-fluoro­benz­yl)-1,1′-ethyl­enediimidazolium tribromidocuprate(I)
title_full 3,3′-Bis(4-fluoro­benz­yl)-1,1′-ethyl­enediimidazolium tribromidocuprate(I)
title_fullStr 3,3′-Bis(4-fluoro­benz­yl)-1,1′-ethyl­enediimidazolium tribromidocuprate(I)
title_full_unstemmed 3,3′-Bis(4-fluoro­benz­yl)-1,1′-ethyl­enediimidazolium tribromidocuprate(I)
title_short 3,3′-Bis(4-fluoro­benz­yl)-1,1′-ethyl­enediimidazolium tribromidocuprate(I)
title_sort 3,3′-bis(4-fluoro­benz­yl)-1,1′-ethyl­enediimidazolium tribromidocuprate(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961950/
https://www.ncbi.nlm.nih.gov/pubmed/21203020
http://dx.doi.org/10.1107/S1600536808021521
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