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Poly[[aqua[μ(3)-(2,6-(2)H(2))-isonicotinato-κ(3) N:O:O′][μ(2)-(2,6-(2)H(2))-isonicotinato-κ(2) N:O]manganese(II)] ethanol solvate]
In the title compound, {[Mn(C(6)H(2)D(2)NO(2))(2)(H(2)O)]·C(2)H(6)O}(n), the Mn(II) metal centre displays a slightly distorted octahedral coordination geometry, provided by three O and two N atoms of five isonicotinate ligands and one O atom of a water molecule. There are two types of isonicotinat...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961953/ https://www.ncbi.nlm.nih.gov/pubmed/21203023 http://dx.doi.org/10.1107/S1600536808016206 |
Sumario: | In the title compound, {[Mn(C(6)H(2)D(2)NO(2))(2)(H(2)O)]·C(2)H(6)O}(n), the Mn(II) metal centre displays a slightly distorted octahedral coordination geometry, provided by three O and two N atoms of five isonicotinate ligands and one O atom of a water molecule. There are two types of isonicotinate anions, one acting as a bridging tridentate group and the other in a bridging bidentate fashion, to form a polymeric three-dimensional network. The structure is stabilized by intra- and intermolecular O—H⋯O and C—H⋯O hydrogen-bond interactions. |
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