Poly[[aqua­[μ(3)-(2,6-(2)H(2))-isonicotinato-κ(3) N:O:O′][μ(2)-(2,6-(2)H(2))-isonicotinato-κ(2) N:O]manganese(II)] ethanol solvate]

In the title compound, {[Mn(C(6)H(2)D(2)NO(2))(2)(H(2)O)]·C(2)H(6)O}(n), the Mn(II) metal centre displays a slightly distorted octa­hedral coordination geometry, provided by three O and two N atoms of five isonicotinate ligands and one O atom of a water mol­ecule. There are two types of isonicotinat...

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Detalles Bibliográficos
Autor principal: Dai, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961953/
https://www.ncbi.nlm.nih.gov/pubmed/21203023
http://dx.doi.org/10.1107/S1600536808016206
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author Dai, Wei
author_facet Dai, Wei
author_sort Dai, Wei
collection PubMed
description In the title compound, {[Mn(C(6)H(2)D(2)NO(2))(2)(H(2)O)]·C(2)H(6)O}(n), the Mn(II) metal centre displays a slightly distorted octa­hedral coordination geometry, provided by three O and two N atoms of five isonicotinate ligands and one O atom of a water mol­ecule. There are two types of isonicotinate anions, one acting as a bridging tridentate group and the other in a bridging bidentate fashion, to form a polymeric three-dimensional network. The structure is stabilized by intra- and inter­molecular O—H⋯O and C—H⋯O hydrogen-bond inter­actions.
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spelling pubmed-29619532010-12-30 Poly[[aqua­[μ(3)-(2,6-(2)H(2))-isonicotinato-κ(3) N:O:O′][μ(2)-(2,6-(2)H(2))-isonicotinato-κ(2) N:O]manganese(II)] ethanol solvate] Dai, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Mn(C(6)H(2)D(2)NO(2))(2)(H(2)O)]·C(2)H(6)O}(n), the Mn(II) metal centre displays a slightly distorted octa­hedral coordination geometry, provided by three O and two N atoms of five isonicotinate ligands and one O atom of a water mol­ecule. There are two types of isonicotinate anions, one acting as a bridging tridentate group and the other in a bridging bidentate fashion, to form a polymeric three-dimensional network. The structure is stabilized by intra- and inter­molecular O—H⋯O and C—H⋯O hydrogen-bond inter­actions. International Union of Crystallography 2008-07-16 /pmc/articles/PMC2961953/ /pubmed/21203023 http://dx.doi.org/10.1107/S1600536808016206 Text en © Wei Dai 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dai, Wei
Poly[[aqua­[μ(3)-(2,6-(2)H(2))-isonicotinato-κ(3) N:O:O′][μ(2)-(2,6-(2)H(2))-isonicotinato-κ(2) N:O]manganese(II)] ethanol solvate]
title Poly[[aqua­[μ(3)-(2,6-(2)H(2))-isonicotinato-κ(3) N:O:O′][μ(2)-(2,6-(2)H(2))-isonicotinato-κ(2) N:O]manganese(II)] ethanol solvate]
title_full Poly[[aqua­[μ(3)-(2,6-(2)H(2))-isonicotinato-κ(3) N:O:O′][μ(2)-(2,6-(2)H(2))-isonicotinato-κ(2) N:O]manganese(II)] ethanol solvate]
title_fullStr Poly[[aqua­[μ(3)-(2,6-(2)H(2))-isonicotinato-κ(3) N:O:O′][μ(2)-(2,6-(2)H(2))-isonicotinato-κ(2) N:O]manganese(II)] ethanol solvate]
title_full_unstemmed Poly[[aqua­[μ(3)-(2,6-(2)H(2))-isonicotinato-κ(3) N:O:O′][μ(2)-(2,6-(2)H(2))-isonicotinato-κ(2) N:O]manganese(II)] ethanol solvate]
title_short Poly[[aqua­[μ(3)-(2,6-(2)H(2))-isonicotinato-κ(3) N:O:O′][μ(2)-(2,6-(2)H(2))-isonicotinato-κ(2) N:O]manganese(II)] ethanol solvate]
title_sort poly[[aqua­[μ(3)-(2,6-(2)h(2))-isonicotinato-κ(3) n:o:o′][μ(2)-(2,6-(2)h(2))-isonicotinato-κ(2) n:o]manganese(ii)] ethanol solvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961953/
https://www.ncbi.nlm.nih.gov/pubmed/21203023
http://dx.doi.org/10.1107/S1600536808016206
work_keys_str_mv AT daiwei polyaquam3262h2isonicotinatok3noom2262h2isonicotinatok2nomanganeseiiethanolsolvate

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