Bis{μ-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}bis­[(thio­cyanato-κN)iron(III)]

The title compound, [Fe(2)(C(16)H(14)N(2)O(2))(2)(NCS)(2)], is isostructural with the Mn(III)-containing analogue. Each Fe(III) atom is chelated by a tetra­dentate 2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolate ligand and by the N atom of a thio­cyanate anion, in a square-pyramidal arran...

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Detalles Bibliográficos
Autores principales: Hao, Lujiang, Mu, Chunhua, Kong, Binbin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961955/
https://www.ncbi.nlm.nih.gov/pubmed/21203025
http://dx.doi.org/10.1107/S1600536808021892
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author Hao, Lujiang
Mu, Chunhua
Kong, Binbin
author_facet Hao, Lujiang
Mu, Chunhua
Kong, Binbin
author_sort Hao, Lujiang
collection PubMed
description The title compound, [Fe(2)(C(16)H(14)N(2)O(2))(2)(NCS)(2)], is isostructural with the Mn(III)-containing analogue. Each Fe(III) atom is chelated by a tetra­dentate 2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolate ligand and by the N atom of a thio­cyanate anion, in a square-pyramidal arrangement. The complex mol­ecules form centrosymmetric dimers, with an Fe—O contact of 2.549 (3) Å, trans to each thio­cyanate anion, completing a distorted octa­hedral coordination geometry.
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spelling pubmed-29619552010-12-30 Bis{μ-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}bis­[(thio­cyanato-κN)iron(III)] Hao, Lujiang Mu, Chunhua Kong, Binbin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(2)(C(16)H(14)N(2)O(2))(2)(NCS)(2)], is isostructural with the Mn(III)-containing analogue. Each Fe(III) atom is chelated by a tetra­dentate 2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolate ligand and by the N atom of a thio­cyanate anion, in a square-pyramidal arrangement. The complex mol­ecules form centrosymmetric dimers, with an Fe—O contact of 2.549 (3) Å, trans to each thio­cyanate anion, completing a distorted octa­hedral coordination geometry. International Union of Crystallography 2008-07-16 /pmc/articles/PMC2961955/ /pubmed/21203025 http://dx.doi.org/10.1107/S1600536808021892 Text en © Hao et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hao, Lujiang
Mu, Chunhua
Kong, Binbin
Bis{μ-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}bis­[(thio­cyanato-κN)iron(III)]
title Bis{μ-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}bis­[(thio­cyanato-κN)iron(III)]
title_full Bis{μ-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}bis­[(thio­cyanato-κN)iron(III)]
title_fullStr Bis{μ-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}bis­[(thio­cyanato-κN)iron(III)]
title_full_unstemmed Bis{μ-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}bis­[(thio­cyanato-κN)iron(III)]
title_short Bis{μ-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}bis­[(thio­cyanato-κN)iron(III)]
title_sort bis{μ-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}bis­[(thio­cyanato-κn)iron(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961955/
https://www.ncbi.nlm.nih.gov/pubmed/21203025
http://dx.doi.org/10.1107/S1600536808021892
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AT muchunhua bism22ethane12diylbisnitrilomethylidynediphenolatobisthiocyanatoknironiii
AT kongbinbin bism22ethane12diylbisnitrilomethylidynediphenolatobisthiocyanatoknironiii

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