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{2,2′-[(2,2-Dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]diphenolato}dioxidomolybdenum(VI)
In the structure of the title compound, [Mo(C(19)H(20)N(2)O(2))O(2)], the Mo atom exhibits oxidation state +VI and is surrounded by two O atoms and the tetradentate Schiff base ligand 2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]diphenolate in a distorted octahedral configurati...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961957/ https://www.ncbi.nlm.nih.gov/pubmed/21203027 http://dx.doi.org/10.1107/S160053680802182X |
Sumario: | In the structure of the title compound, [Mo(C(19)H(20)N(2)O(2))O(2)], the Mo atom exhibits oxidation state +VI and is surrounded by two O atoms and the tetradentate Schiff base ligand 2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]diphenolate in a distorted octahedral configuration. An intramolecular C—H⋯O hydrogen bond between a methylene group and one O atom of the O=Mo(VI)=O unit, as well as additional intermolecular hydrogen bonds between neighboring molecules, lead to a weakly bonded inversion-symmetric dimeric structure. |
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