Dichlorido(dimethyl­formamide-κO)[1,4,7-tris­(2-cyano­ethyl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]cobalt(II)

The title compound, [CoCl(2)(C(15)H(24)N(6))(C(3)H(7)NO)], crystallizes as a monomeric complex. The coordination environment around the Co(II) center could be described as a distorted octa­hedron consisting of three N donors from the facially coordinating triaza macrocyclic ligand, one O donor from...

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Detalles Bibliográficos
Autores principales: Zhang, Zhong, Geng, Zhi-Rong, Zhao, Qun, Wang, Zhi-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961961/
https://www.ncbi.nlm.nih.gov/pubmed/21203031
http://dx.doi.org/10.1107/S160053680802179X
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author Zhang, Zhong
Geng, Zhi-Rong
Zhao, Qun
Wang, Zhi-Lin
author_facet Zhang, Zhong
Geng, Zhi-Rong
Zhao, Qun
Wang, Zhi-Lin
author_sort Zhang, Zhong
collection PubMed
description The title compound, [CoCl(2)(C(15)H(24)N(6))(C(3)H(7)NO)], crystallizes as a monomeric complex. The coordination environment around the Co(II) center could be described as a distorted octa­hedron consisting of three N donors from the facially coordinating triaza macrocyclic ligand, one O donor from dimethyl­formamide and two Cl(−) ions. Neutral complex mol­ecules are associated via inter­molecular C—H⋯Cl hydrogen bonds to form two-dimensional layers. C—H⋯O hydrogen bonds are also present.
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spelling pubmed-29619612010-12-30 Dichlorido(dimethyl­formamide-κO)[1,4,7-tris­(2-cyano­ethyl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]cobalt(II) Zhang, Zhong Geng, Zhi-Rong Zhao, Qun Wang, Zhi-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [CoCl(2)(C(15)H(24)N(6))(C(3)H(7)NO)], crystallizes as a monomeric complex. The coordination environment around the Co(II) center could be described as a distorted octa­hedron consisting of three N donors from the facially coordinating triaza macrocyclic ligand, one O donor from dimethyl­formamide and two Cl(−) ions. Neutral complex mol­ecules are associated via inter­molecular C—H⋯Cl hydrogen bonds to form two-dimensional layers. C—H⋯O hydrogen bonds are also present. International Union of Crystallography 2008-07-19 /pmc/articles/PMC2961961/ /pubmed/21203031 http://dx.doi.org/10.1107/S160053680802179X Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Zhong
Geng, Zhi-Rong
Zhao, Qun
Wang, Zhi-Lin
Dichlorido(dimethyl­formamide-κO)[1,4,7-tris­(2-cyano­ethyl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]cobalt(II)
title Dichlorido(dimethyl­formamide-κO)[1,4,7-tris­(2-cyano­ethyl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]cobalt(II)
title_full Dichlorido(dimethyl­formamide-κO)[1,4,7-tris­(2-cyano­ethyl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]cobalt(II)
title_fullStr Dichlorido(dimethyl­formamide-κO)[1,4,7-tris­(2-cyano­ethyl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]cobalt(II)
title_full_unstemmed Dichlorido(dimethyl­formamide-κO)[1,4,7-tris­(2-cyano­ethyl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]cobalt(II)
title_short Dichlorido(dimethyl­formamide-κO)[1,4,7-tris­(2-cyano­ethyl)-1,4,7-triaza­cyclo­nonane-κ(3) N (1),N (4),N (7)]cobalt(II)
title_sort dichlorido(dimethyl­formamide-κo)[1,4,7-tris­(2-cyano­ethyl)-1,4,7-triaza­cyclo­nonane-κ(3) n (1),n (4),n (7)]cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961961/
https://www.ncbi.nlm.nih.gov/pubmed/21203031
http://dx.doi.org/10.1107/S160053680802179X
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