Bis{μ-4-chloro-2-[(2-pyridyleth­yl)imino­meth­yl]phenolato}bis­[chloridocopper(II)]

The title compound, [Cu(2)(C(14)H(12)ClN(2)O)(2)Cl(2)], is a copper(II) dimer where the metal centres are bridged by O atoms from a 5-chloro­salicylaldehyde group. The coordination geometry of each copper(II) centre is distorted square-pyramidal, with two N atoms from a 2-ethyl­amino­pyridine group...

Descripción completa

Detalles Bibliográficos
Autor principal: Suo, Jianlan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961964/
https://www.ncbi.nlm.nih.gov/pubmed/21203034
http://dx.doi.org/10.1107/S1600536808022162
_version_ 1782189108229046272
author Suo, Jianlan
author_facet Suo, Jianlan
author_sort Suo, Jianlan
collection PubMed
description The title compound, [Cu(2)(C(14)H(12)ClN(2)O)(2)Cl(2)], is a copper(II) dimer where the metal centres are bridged by O atoms from a 5-chloro­salicylaldehyde group. The coordination geometry of each copper(II) centre is distorted square-pyramidal, with two N atoms from a 2-ethyl­amino­pyridine group and two O atoms from a 5-chloro­salicylaldehyde group occupying the basal positions, and with a Cl atom at the apical position. The dimer is centrosymmetric, with a crystallographic inversion centre midway between the two Cu atoms [Cu⋯Cu = 3.103 (9) Å].
format Text
id pubmed-2961964
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29619642010-12-30 Bis{μ-4-chloro-2-[(2-pyridyleth­yl)imino­meth­yl]phenolato}bis­[chloridocopper(II)] Suo, Jianlan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(C(14)H(12)ClN(2)O)(2)Cl(2)], is a copper(II) dimer where the metal centres are bridged by O atoms from a 5-chloro­salicylaldehyde group. The coordination geometry of each copper(II) centre is distorted square-pyramidal, with two N atoms from a 2-ethyl­amino­pyridine group and two O atoms from a 5-chloro­salicylaldehyde group occupying the basal positions, and with a Cl atom at the apical position. The dimer is centrosymmetric, with a crystallographic inversion centre midway between the two Cu atoms [Cu⋯Cu = 3.103 (9) Å]. International Union of Crystallography 2008-07-19 /pmc/articles/PMC2961964/ /pubmed/21203034 http://dx.doi.org/10.1107/S1600536808022162 Text en © Jianlan Suo 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Suo, Jianlan
Bis{μ-4-chloro-2-[(2-pyridyleth­yl)imino­meth­yl]phenolato}bis­[chloridocopper(II)]
title Bis{μ-4-chloro-2-[(2-pyridyleth­yl)imino­meth­yl]phenolato}bis­[chloridocopper(II)]
title_full Bis{μ-4-chloro-2-[(2-pyridyleth­yl)imino­meth­yl]phenolato}bis­[chloridocopper(II)]
title_fullStr Bis{μ-4-chloro-2-[(2-pyridyleth­yl)imino­meth­yl]phenolato}bis­[chloridocopper(II)]
title_full_unstemmed Bis{μ-4-chloro-2-[(2-pyridyleth­yl)imino­meth­yl]phenolato}bis­[chloridocopper(II)]
title_short Bis{μ-4-chloro-2-[(2-pyridyleth­yl)imino­meth­yl]phenolato}bis­[chloridocopper(II)]
title_sort bis{μ-4-chloro-2-[(2-pyridyleth­yl)imino­meth­yl]phenolato}bis­[chloridocopper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961964/
https://www.ncbi.nlm.nih.gov/pubmed/21203034
http://dx.doi.org/10.1107/S1600536808022162
work_keys_str_mv AT suojianlan bism4chloro22pyridylethyliminomethylphenolatobischloridocopperii

Ejemplares similares