Bis{μ-2-(1H-indol-3-yl)-N′-[1-(5-methyl-2-oxidophen­yl)ethyl­idene]­aceto­hydraz­idato}bis­[aqua­zinc(II)] dimethyl sulfoxide tetra­solvate

The dinuclear title compound, [Zn(2)(C(19)H(17)N(3)O(2))(2)(H(2)O)(2)]·4C(2)H(6)OS, lies about a center of inversion. The deprotonated monoanion O,N,O-chelates the Zn atom; the hydr­oxy O atom also engages in bonding to the symmetry-related Zn atom so that one N and three O atoms form a square aroun...

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Autores principales: Zuraini, Kadir, Ali, Hapipah M., Puvaneswary, Subramaniam, Robinson, Ward T., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961965/
https://www.ncbi.nlm.nih.gov/pubmed/21203035
http://dx.doi.org/10.1107/S1600536808022034
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author Zuraini, Kadir
Ali, Hapipah M.
Puvaneswary, Subramaniam
Robinson, Ward T.
Ng, Seik Weng
author_facet Zuraini, Kadir
Ali, Hapipah M.
Puvaneswary, Subramaniam
Robinson, Ward T.
Ng, Seik Weng
author_sort Zuraini, Kadir
collection PubMed
description The dinuclear title compound, [Zn(2)(C(19)H(17)N(3)O(2))(2)(H(2)O)(2)]·4C(2)H(6)OS, lies about a center of inversion. The deprotonated monoanion O,N,O-chelates the Zn atom; the hydr­oxy O atom also engages in bonding to the symmetry-related Zn atom so that one N and three O atoms form a square around the metal. The coordination geometry is square-pyramidal, with the apical site occupied by a water mol­ecule. Hydrogen bonds, with the water mol­ecule serving as donor atom, lead to the formation of a linear chain motif. There is an N—H⋯O hydrogen bond between the complex molecule and solvent O atom.
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spelling pubmed-29619652010-12-30 Bis{μ-2-(1H-indol-3-yl)-N′-[1-(5-methyl-2-oxidophen­yl)ethyl­idene]­aceto­hydraz­idato}bis­[aqua­zinc(II)] dimethyl sulfoxide tetra­solvate Zuraini, Kadir Ali, Hapipah M. Puvaneswary, Subramaniam Robinson, Ward T. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title compound, [Zn(2)(C(19)H(17)N(3)O(2))(2)(H(2)O)(2)]·4C(2)H(6)OS, lies about a center of inversion. The deprotonated monoanion O,N,O-chelates the Zn atom; the hydr­oxy O atom also engages in bonding to the symmetry-related Zn atom so that one N and three O atoms form a square around the metal. The coordination geometry is square-pyramidal, with the apical site occupied by a water mol­ecule. Hydrogen bonds, with the water mol­ecule serving as donor atom, lead to the formation of a linear chain motif. There is an N—H⋯O hydrogen bond between the complex molecule and solvent O atom. International Union of Crystallography 2008-07-19 /pmc/articles/PMC2961965/ /pubmed/21203035 http://dx.doi.org/10.1107/S1600536808022034 Text en © Zuraini et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zuraini, Kadir
Ali, Hapipah M.
Puvaneswary, Subramaniam
Robinson, Ward T.
Ng, Seik Weng
Bis{μ-2-(1H-indol-3-yl)-N′-[1-(5-methyl-2-oxidophen­yl)ethyl­idene]­aceto­hydraz­idato}bis­[aqua­zinc(II)] dimethyl sulfoxide tetra­solvate
title Bis{μ-2-(1H-indol-3-yl)-N′-[1-(5-methyl-2-oxidophen­yl)ethyl­idene]­aceto­hydraz­idato}bis­[aqua­zinc(II)] dimethyl sulfoxide tetra­solvate
title_full Bis{μ-2-(1H-indol-3-yl)-N′-[1-(5-methyl-2-oxidophen­yl)ethyl­idene]­aceto­hydraz­idato}bis­[aqua­zinc(II)] dimethyl sulfoxide tetra­solvate
title_fullStr Bis{μ-2-(1H-indol-3-yl)-N′-[1-(5-methyl-2-oxidophen­yl)ethyl­idene]­aceto­hydraz­idato}bis­[aqua­zinc(II)] dimethyl sulfoxide tetra­solvate
title_full_unstemmed Bis{μ-2-(1H-indol-3-yl)-N′-[1-(5-methyl-2-oxidophen­yl)ethyl­idene]­aceto­hydraz­idato}bis­[aqua­zinc(II)] dimethyl sulfoxide tetra­solvate
title_short Bis{μ-2-(1H-indol-3-yl)-N′-[1-(5-methyl-2-oxidophen­yl)ethyl­idene]­aceto­hydraz­idato}bis­[aqua­zinc(II)] dimethyl sulfoxide tetra­solvate
title_sort bis{μ-2-(1h-indol-3-yl)-n′-[1-(5-methyl-2-oxidophen­yl)ethyl­idene]­aceto­hydraz­idato}bis­[aqua­zinc(ii)] dimethyl sulfoxide tetra­solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961965/
https://www.ncbi.nlm.nih.gov/pubmed/21203035
http://dx.doi.org/10.1107/S1600536808022034
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