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μ-2,3,5,6-Tetra-2-pyridylpyrazine-κ(3) N (1),N (2),N (6):κ(3) N (3),N (4),N (5)-bis­[(methanol-κO)(nitrato-κ(2) O,O′)(nitrato-κO)cadmium(II)]

The title complex, [Cd(2)(NO(3))(4)(C(24)H(16)N(6))(CH(4)O)(2)], displays a centrosymmetric dinuclear structure, in which the 2,3,5,6-tetra-2-pyridinylpyrazine (tppz) ligand links two Cd ions separated by 7.323 (4) Å. Each Cd(II) center is seven-coordinated by three N-atom donors of tppz in one plan...

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Detalles Bibliográficos
Autores principales: Seyed Sadjadi, Mirabdullah, Ebadi, Amin, Zare, Karim, Amani, Vahid, Khavasi, Hamid Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961967/
https://www.ncbi.nlm.nih.gov/pubmed/21203037
http://dx.doi.org/10.1107/S1600536808022320
Descripción
Sumario:The title complex, [Cd(2)(NO(3))(4)(C(24)H(16)N(6))(CH(4)O)(2)], displays a centrosymmetric dinuclear structure, in which the 2,3,5,6-tetra-2-pyridinylpyrazine (tppz) ligand links two Cd ions separated by 7.323 (4) Å. Each Cd(II) center is seven-coordinated by three N-atom donors of tppz in one plane, by two O atoms nearly normal to this plane, and by two O atoms 0.393 (3) and 0.488 (3) Å from that plane. The two Cd(II) ions are above and below the plane of the pyrazine ring of the tppz ligand, oriented with respect to the pyridine rings at dihedral angles of 38.01 (3) and 31.90 (3)°. The dihedral angle between the two pyridine rings is 41.11 (3)°. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules.