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Tetra­aqua­(1,10-phenanthroline-κ(2) N,N′)magnesium(II) bis­[(2,4-dichloro­phen­yl)acetate]

In the mononuclear title complex, [Mg(C(12)H(8)N(2))(H(2)O)(4)](C(8)H(5)Cl(2)O(2))(2), each Mg(II) ion is hexa­coordinated by two N atoms from a 1,10-phenanthroline ligand [Mg—N = 2.233 (2) Å] and four water mol­ecules [Mg—OW = 2.033 (2) and 2.043 (1) Å] in a distorted octa­hedral geometry. A twofol...

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Detalles Bibliográficos
Autores principales: Hao, Xiao-Min, Gu, Chang-Sheng, Song, Weng-Dong, Liu, Ji-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961968/
https://www.ncbi.nlm.nih.gov/pubmed/21203038
http://dx.doi.org/10.1107/S1600536808022150
Descripción
Sumario:In the mononuclear title complex, [Mg(C(12)H(8)N(2))(H(2)O)(4)](C(8)H(5)Cl(2)O(2))(2), each Mg(II) ion is hexa­coordinated by two N atoms from a 1,10-phenanthroline ligand [Mg—N = 2.233 (2) Å] and four water mol­ecules [Mg—OW = 2.033 (2) and 2.043 (1) Å] in a distorted octa­hedral geometry. A twofold rotation axis passes through the Mg atom. In the crystal structure, the cations and anions are linked by inter­molecular O—H⋯O hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance = 3.804 (2) Å] into layers parallel to the ac plane.