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Tetraaqua(1,10-phenanthroline-κ(2) N,N′)magnesium(II) bis[(2,4-dichlorophenyl)acetate]
In the mononuclear title complex, [Mg(C(12)H(8)N(2))(H(2)O)(4)](C(8)H(5)Cl(2)O(2))(2), each Mg(II) ion is hexacoordinated by two N atoms from a 1,10-phenanthroline ligand [Mg—N = 2.233 (2) Å] and four water molecules [Mg—OW = 2.033 (2) and 2.043 (1) Å] in a distorted octahedral geometry. A twofol...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961968/ https://www.ncbi.nlm.nih.gov/pubmed/21203038 http://dx.doi.org/10.1107/S1600536808022150 |
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author | Hao, Xiao-Min Gu, Chang-Sheng Song, Weng-Dong Liu, Ji-Wei |
author_facet | Hao, Xiao-Min Gu, Chang-Sheng Song, Weng-Dong Liu, Ji-Wei |
author_sort | Hao, Xiao-Min |
collection | PubMed |
description | In the mononuclear title complex, [Mg(C(12)H(8)N(2))(H(2)O)(4)](C(8)H(5)Cl(2)O(2))(2), each Mg(II) ion is hexacoordinated by two N atoms from a 1,10-phenanthroline ligand [Mg—N = 2.233 (2) Å] and four water molecules [Mg—OW = 2.033 (2) and 2.043 (1) Å] in a distorted octahedral geometry. A twofold rotation axis passes through the Mg atom. In the crystal structure, the cations and anions are linked by intermolecular O—H⋯O hydrogen bonds and π–π stacking interactions [centroid–centroid distance = 3.804 (2) Å] into layers parallel to the ac plane. |
format | Text |
id | pubmed-2961968 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29619682010-12-30 Tetraaqua(1,10-phenanthroline-κ(2) N,N′)magnesium(II) bis[(2,4-dichlorophenyl)acetate] Hao, Xiao-Min Gu, Chang-Sheng Song, Weng-Dong Liu, Ji-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Mg(C(12)H(8)N(2))(H(2)O)(4)](C(8)H(5)Cl(2)O(2))(2), each Mg(II) ion is hexacoordinated by two N atoms from a 1,10-phenanthroline ligand [Mg—N = 2.233 (2) Å] and four water molecules [Mg—OW = 2.033 (2) and 2.043 (1) Å] in a distorted octahedral geometry. A twofold rotation axis passes through the Mg atom. In the crystal structure, the cations and anions are linked by intermolecular O—H⋯O hydrogen bonds and π–π stacking interactions [centroid–centroid distance = 3.804 (2) Å] into layers parallel to the ac plane. International Union of Crystallography 2008-07-23 /pmc/articles/PMC2961968/ /pubmed/21203038 http://dx.doi.org/10.1107/S1600536808022150 Text en © Hao et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hao, Xiao-Min Gu, Chang-Sheng Song, Weng-Dong Liu, Ji-Wei Tetraaqua(1,10-phenanthroline-κ(2) N,N′)magnesium(II) bis[(2,4-dichlorophenyl)acetate] |
title | Tetraaqua(1,10-phenanthroline-κ(2)
N,N′)magnesium(II) bis[(2,4-dichlorophenyl)acetate] |
title_full | Tetraaqua(1,10-phenanthroline-κ(2)
N,N′)magnesium(II) bis[(2,4-dichlorophenyl)acetate] |
title_fullStr | Tetraaqua(1,10-phenanthroline-κ(2)
N,N′)magnesium(II) bis[(2,4-dichlorophenyl)acetate] |
title_full_unstemmed | Tetraaqua(1,10-phenanthroline-κ(2)
N,N′)magnesium(II) bis[(2,4-dichlorophenyl)acetate] |
title_short | Tetraaqua(1,10-phenanthroline-κ(2)
N,N′)magnesium(II) bis[(2,4-dichlorophenyl)acetate] |
title_sort | tetraaqua(1,10-phenanthroline-κ(2)
n,n′)magnesium(ii) bis[(2,4-dichlorophenyl)acetate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961968/ https://www.ncbi.nlm.nih.gov/pubmed/21203038 http://dx.doi.org/10.1107/S1600536808022150 |
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