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Tetra­aqua­(1,10-phenanthroline-κ(2) N,N′)magnesium(II) bis­[(2,4-dichloro­phen­yl)acetate]

In the mononuclear title complex, [Mg(C(12)H(8)N(2))(H(2)O)(4)](C(8)H(5)Cl(2)O(2))(2), each Mg(II) ion is hexa­coordinated by two N atoms from a 1,10-phenanthroline ligand [Mg—N = 2.233 (2) Å] and four water mol­ecules [Mg—OW = 2.033 (2) and 2.043 (1) Å] in a distorted octa­hedral geometry. A twofol...

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Detalles Bibliográficos
Autores principales: Hao, Xiao-Min, Gu, Chang-Sheng, Song, Weng-Dong, Liu, Ji-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961968/
https://www.ncbi.nlm.nih.gov/pubmed/21203038
http://dx.doi.org/10.1107/S1600536808022150
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author Hao, Xiao-Min
Gu, Chang-Sheng
Song, Weng-Dong
Liu, Ji-Wei
author_facet Hao, Xiao-Min
Gu, Chang-Sheng
Song, Weng-Dong
Liu, Ji-Wei
author_sort Hao, Xiao-Min
collection PubMed
description In the mononuclear title complex, [Mg(C(12)H(8)N(2))(H(2)O)(4)](C(8)H(5)Cl(2)O(2))(2), each Mg(II) ion is hexa­coordinated by two N atoms from a 1,10-phenanthroline ligand [Mg—N = 2.233 (2) Å] and four water mol­ecules [Mg—OW = 2.033 (2) and 2.043 (1) Å] in a distorted octa­hedral geometry. A twofold rotation axis passes through the Mg atom. In the crystal structure, the cations and anions are linked by inter­molecular O—H⋯O hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance = 3.804 (2) Å] into layers parallel to the ac plane.
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spelling pubmed-29619682010-12-30 Tetra­aqua­(1,10-phenanthroline-κ(2) N,N′)magnesium(II) bis­[(2,4-dichloro­phen­yl)acetate] Hao, Xiao-Min Gu, Chang-Sheng Song, Weng-Dong Liu, Ji-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Mg(C(12)H(8)N(2))(H(2)O)(4)](C(8)H(5)Cl(2)O(2))(2), each Mg(II) ion is hexa­coordinated by two N atoms from a 1,10-phenanthroline ligand [Mg—N = 2.233 (2) Å] and four water mol­ecules [Mg—OW = 2.033 (2) and 2.043 (1) Å] in a distorted octa­hedral geometry. A twofold rotation axis passes through the Mg atom. In the crystal structure, the cations and anions are linked by inter­molecular O—H⋯O hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance = 3.804 (2) Å] into layers parallel to the ac plane. International Union of Crystallography 2008-07-23 /pmc/articles/PMC2961968/ /pubmed/21203038 http://dx.doi.org/10.1107/S1600536808022150 Text en © Hao et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hao, Xiao-Min
Gu, Chang-Sheng
Song, Weng-Dong
Liu, Ji-Wei
Tetra­aqua­(1,10-phenanthroline-κ(2) N,N′)magnesium(II) bis­[(2,4-dichloro­phen­yl)acetate]
title Tetra­aqua­(1,10-phenanthroline-κ(2) N,N′)magnesium(II) bis­[(2,4-dichloro­phen­yl)acetate]
title_full Tetra­aqua­(1,10-phenanthroline-κ(2) N,N′)magnesium(II) bis­[(2,4-dichloro­phen­yl)acetate]
title_fullStr Tetra­aqua­(1,10-phenanthroline-κ(2) N,N′)magnesium(II) bis­[(2,4-dichloro­phen­yl)acetate]
title_full_unstemmed Tetra­aqua­(1,10-phenanthroline-κ(2) N,N′)magnesium(II) bis­[(2,4-dichloro­phen­yl)acetate]
title_short Tetra­aqua­(1,10-phenanthroline-κ(2) N,N′)magnesium(II) bis­[(2,4-dichloro­phen­yl)acetate]
title_sort tetra­aqua­(1,10-phenanthroline-κ(2) n,n′)magnesium(ii) bis­[(2,4-dichloro­phen­yl)acetate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961968/
https://www.ncbi.nlm.nih.gov/pubmed/21203038
http://dx.doi.org/10.1107/S1600536808022150
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