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Di-μ-chlorido-bis[dichlorido(3,3′,5,5′-tetramethyl-4,4′-bipyrazol-1-ium-κN (2′))copper(II)] dihydrate
The structure of the centrosymmetric title compound, [Cu(2)Cl(6)(C(10)H(15)N(4))(2)]·2H(2)O, consists of a dimeric [{(HMe(4)bpz)CuCl(3)}(2)] unit (HMe(4)bpz is 3,3′,5,5′-tetramethyl-4,4′-bipyrazol-1-ium) with two solvent water molecules. Each [HMe(4)bpz](+) cation is bonded to a CuCl(3) unit throug...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961969/ https://www.ncbi.nlm.nih.gov/pubmed/21203039 http://dx.doi.org/10.1107/S1600536808022605 |
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author | Kurawa, Mukhtar A. Adams, Christopher J. Orpen, A. Guy |
author_facet | Kurawa, Mukhtar A. Adams, Christopher J. Orpen, A. Guy |
author_sort | Kurawa, Mukhtar A. |
collection | PubMed |
description | The structure of the centrosymmetric title compound, [Cu(2)Cl(6)(C(10)H(15)N(4))(2)]·2H(2)O, consists of a dimeric [{(HMe(4)bpz)CuCl(3)}(2)] unit (HMe(4)bpz is 3,3′,5,5′-tetramethyl-4,4′-bipyrazol-1-ium) with two solvent water molecules. Each [HMe(4)bpz](+) cation is bonded to a CuCl(3) unit through a Cu—N dative bond, effectively making square-planar geometry at the Cu atom. Two of these units then undergo a face-to-face dimerization so that the Cu atoms have a Jahn–Teller distorted square-pyramidal geometry with three chlorides and an N atom in the basal plane and one chloride weakly bound in the apical position. Several N—H⋯Cl, O—H⋯Cl and N—H⋯O hydrogen bonds form a three-dimensional network. |
format | Text |
id | pubmed-2961969 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29619692010-12-30 Di-μ-chlorido-bis[dichlorido(3,3′,5,5′-tetramethyl-4,4′-bipyrazol-1-ium-κN (2′))copper(II)] dihydrate Kurawa, Mukhtar A. Adams, Christopher J. Orpen, A. Guy Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the centrosymmetric title compound, [Cu(2)Cl(6)(C(10)H(15)N(4))(2)]·2H(2)O, consists of a dimeric [{(HMe(4)bpz)CuCl(3)}(2)] unit (HMe(4)bpz is 3,3′,5,5′-tetramethyl-4,4′-bipyrazol-1-ium) with two solvent water molecules. Each [HMe(4)bpz](+) cation is bonded to a CuCl(3) unit through a Cu—N dative bond, effectively making square-planar geometry at the Cu atom. Two of these units then undergo a face-to-face dimerization so that the Cu atoms have a Jahn–Teller distorted square-pyramidal geometry with three chlorides and an N atom in the basal plane and one chloride weakly bound in the apical position. Several N—H⋯Cl, O—H⋯Cl and N—H⋯O hydrogen bonds form a three-dimensional network. International Union of Crystallography 2008-07-23 /pmc/articles/PMC2961969/ /pubmed/21203039 http://dx.doi.org/10.1107/S1600536808022605 Text en © Kurawa et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kurawa, Mukhtar A. Adams, Christopher J. Orpen, A. Guy Di-μ-chlorido-bis[dichlorido(3,3′,5,5′-tetramethyl-4,4′-bipyrazol-1-ium-κN (2′))copper(II)] dihydrate |
title | Di-μ-chlorido-bis[dichlorido(3,3′,5,5′-tetramethyl-4,4′-bipyrazol-1-ium-κN
(2′))copper(II)] dihydrate |
title_full | Di-μ-chlorido-bis[dichlorido(3,3′,5,5′-tetramethyl-4,4′-bipyrazol-1-ium-κN
(2′))copper(II)] dihydrate |
title_fullStr | Di-μ-chlorido-bis[dichlorido(3,3′,5,5′-tetramethyl-4,4′-bipyrazol-1-ium-κN
(2′))copper(II)] dihydrate |
title_full_unstemmed | Di-μ-chlorido-bis[dichlorido(3,3′,5,5′-tetramethyl-4,4′-bipyrazol-1-ium-κN
(2′))copper(II)] dihydrate |
title_short | Di-μ-chlorido-bis[dichlorido(3,3′,5,5′-tetramethyl-4,4′-bipyrazol-1-ium-κN
(2′))copper(II)] dihydrate |
title_sort | di-μ-chlorido-bis[dichlorido(3,3′,5,5′-tetramethyl-4,4′-bipyrazol-1-ium-κn
(2′))copper(ii)] dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961969/ https://www.ncbi.nlm.nih.gov/pubmed/21203039 http://dx.doi.org/10.1107/S1600536808022605 |
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