Cargando…
catena-Poly[μ-aqua-2:1′κ(2) O:O-aqua-2κO-(2-fluorobenzoato-1κ(2) O,O′)(μ(2)-2-fluorobenzoato-2′:1κ(2) O:O′)bis(μ(3)-2-fluorobenzoato)-2′:1:2κ(4) O:O,O′:O′;1:2:1′κ(5) F,O:O,O′:O′-dilead(II)]
In the title compound, [Pb(2)(C(7)H(4)FO(2))(4)(H(2)O)(2)](n), one Pb(II) atom is coordinated by seven O atoms and one F atom from five 2-fluorobenzoate ligands, and the other Pb(II) atom is coordinated by five O atoms from four 2-fluorobenzoate ligands and three water molecules, resulting in dis...
| Autor principal: | |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961970/ https://www.ncbi.nlm.nih.gov/pubmed/21203040 http://dx.doi.org/10.1107/S1600536808022678 |
| _version_ | 1782189109705441280 |
|---|---|
| author | Zhang, Bi-Song |
| author_facet | Zhang, Bi-Song |
| author_sort | Zhang, Bi-Song |
| collection | PubMed |
| description | In the title compound, [Pb(2)(C(7)H(4)FO(2))(4)(H(2)O)(2)](n), one Pb(II) atom is coordinated by seven O atoms and one F atom from five 2-fluorobenzoate ligands, and the other Pb(II) atom is coordinated by five O atoms from four 2-fluorobenzoate ligands and three water molecules, resulting in distorted PbO(7)F and PbO(8) polyhedra. The 2-fluorobenzoate ligands bridge Pb atoms, giving rise to a one-dimensional chain structure extending along the [100] direction. The polymeric chains are connected via C—H⋯O hydrogen bonds and π–π interactions, with an interplanar distance of 3.46 (1) Å. An intramolecular O—H⋯F interaction is also present. |
| format | Text |
| id | pubmed-2961970 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29619702010-12-30 catena-Poly[μ-aqua-2:1′κ(2) O:O-aqua-2κO-(2-fluorobenzoato-1κ(2) O,O′)(μ(2)-2-fluorobenzoato-2′:1κ(2) O:O′)bis(μ(3)-2-fluorobenzoato)-2′:1:2κ(4) O:O,O′:O′;1:2:1′κ(5) F,O:O,O′:O′-dilead(II)] Zhang, Bi-Song Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pb(2)(C(7)H(4)FO(2))(4)(H(2)O)(2)](n), one Pb(II) atom is coordinated by seven O atoms and one F atom from five 2-fluorobenzoate ligands, and the other Pb(II) atom is coordinated by five O atoms from four 2-fluorobenzoate ligands and three water molecules, resulting in distorted PbO(7)F and PbO(8) polyhedra. The 2-fluorobenzoate ligands bridge Pb atoms, giving rise to a one-dimensional chain structure extending along the [100] direction. The polymeric chains are connected via C—H⋯O hydrogen bonds and π–π interactions, with an interplanar distance of 3.46 (1) Å. An intramolecular O—H⋯F interaction is also present. International Union of Crystallography 2008-07-23 /pmc/articles/PMC2961970/ /pubmed/21203040 http://dx.doi.org/10.1107/S1600536808022678 Text en © Bi-Song Zhang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Bi-Song catena-Poly[μ-aqua-2:1′κ(2) O:O-aqua-2κO-(2-fluorobenzoato-1κ(2) O,O′)(μ(2)-2-fluorobenzoato-2′:1κ(2) O:O′)bis(μ(3)-2-fluorobenzoato)-2′:1:2κ(4) O:O,O′:O′;1:2:1′κ(5) F,O:O,O′:O′-dilead(II)] |
| title |
catena-Poly[μ-aqua-2:1′κ(2)
O:O-aqua-2κO-(2-fluorobenzoato-1κ(2)
O,O′)(μ(2)-2-fluorobenzoato-2′:1κ(2)
O:O′)bis(μ(3)-2-fluorobenzoato)-2′:1:2κ(4)
O:O,O′:O′;1:2:1′κ(5)
F,O:O,O′:O′-dilead(II)] |
| title_full |
catena-Poly[μ-aqua-2:1′κ(2)
O:O-aqua-2κO-(2-fluorobenzoato-1κ(2)
O,O′)(μ(2)-2-fluorobenzoato-2′:1κ(2)
O:O′)bis(μ(3)-2-fluorobenzoato)-2′:1:2κ(4)
O:O,O′:O′;1:2:1′κ(5)
F,O:O,O′:O′-dilead(II)] |
| title_fullStr |
catena-Poly[μ-aqua-2:1′κ(2)
O:O-aqua-2κO-(2-fluorobenzoato-1κ(2)
O,O′)(μ(2)-2-fluorobenzoato-2′:1κ(2)
O:O′)bis(μ(3)-2-fluorobenzoato)-2′:1:2κ(4)
O:O,O′:O′;1:2:1′κ(5)
F,O:O,O′:O′-dilead(II)] |
| title_full_unstemmed |
catena-Poly[μ-aqua-2:1′κ(2)
O:O-aqua-2κO-(2-fluorobenzoato-1κ(2)
O,O′)(μ(2)-2-fluorobenzoato-2′:1κ(2)
O:O′)bis(μ(3)-2-fluorobenzoato)-2′:1:2κ(4)
O:O,O′:O′;1:2:1′κ(5)
F,O:O,O′:O′-dilead(II)] |
| title_short |
catena-Poly[μ-aqua-2:1′κ(2)
O:O-aqua-2κO-(2-fluorobenzoato-1κ(2)
O,O′)(μ(2)-2-fluorobenzoato-2′:1κ(2)
O:O′)bis(μ(3)-2-fluorobenzoato)-2′:1:2κ(4)
O:O,O′:O′;1:2:1′κ(5)
F,O:O,O′:O′-dilead(II)] |
| title_sort | catena-poly[μ-aqua-2:1′κ(2)
o:o-aqua-2κo-(2-fluorobenzoato-1κ(2)
o,o′)(μ(2)-2-fluorobenzoato-2′:1κ(2)
o:o′)bis(μ(3)-2-fluorobenzoato)-2′:1:2κ(4)
o:o,o′:o′;1:2:1′κ(5)
f,o:o,o′:o′-dilead(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961970/ https://www.ncbi.nlm.nih.gov/pubmed/21203040 http://dx.doi.org/10.1107/S1600536808022678 |
| work_keys_str_mv | AT zhangbisong catenapolymaqua21k2ooaqua2ko2fluorobenzoato1k2oom22fluorobenzoato21k2oobism32fluorobenzoato212k4oooo121k5foooodileadii |