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Di-μ-chlorido-bis­{[2-(morpholinometh­yl)phenyl-κ(2) C (1),N]palladium(II)}

The title compound, [Pd(2)(C(11)H(14)NO)(2)Cl(2)], has a dimeric structure with Cl atoms bridging the two Pd atoms, one half of the mol­ecule being generated by symmetry due to the crystallographic inversion centre located in the middle of the perfectly planar Pd(2)Cl(2) ring. The five-membered ring...

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Detalles Bibliográficos
Autores principales: Copolovici, Dana, Silvestru, Cristian, Isaia, Francesco, Varga, Richard A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961971/
https://www.ncbi.nlm.nih.gov/pubmed/21203041
http://dx.doi.org/10.1107/S1600536808022575
Descripción
Sumario:The title compound, [Pd(2)(C(11)H(14)NO)(2)Cl(2)], has a dimeric structure with Cl atoms bridging the two Pd atoms, one half of the mol­ecule being generated by symmetry due to the crystallographic inversion centre located in the middle of the perfectly planar Pd(2)Cl(2) ring. The five-membered ring adopts an envelope conformation, while the morpholino group has a chair conformation. The geometry around the metal centres is distorted square-planar, as a result of a strong intra­molecular N→Pd coordination trans to a Pd—Cl bond. In the crystal structure, the dimeric structure is strengthened by inter­molecular C—H⋯Cl hydrogen bonds. C—H⋯C(phen­yl) inter­actions link the dimers into a columnar supra­molecular array along the a axis; the dimers are further connected by C—H⋯Ph inter­actions into a three-dimensional supra­molecular arrangement.