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Di-μ-chlorido-bis­{[2-(morpholinometh­yl)phenyl-κ(2) C (1),N]palladium(II)}

The title compound, [Pd(2)(C(11)H(14)NO)(2)Cl(2)], has a dimeric structure with Cl atoms bridging the two Pd atoms, one half of the mol­ecule being generated by symmetry due to the crystallographic inversion centre located in the middle of the perfectly planar Pd(2)Cl(2) ring. The five-membered ring...

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Detalles Bibliográficos
Autores principales: Copolovici, Dana, Silvestru, Cristian, Isaia, Francesco, Varga, Richard A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961971/
https://www.ncbi.nlm.nih.gov/pubmed/21203041
http://dx.doi.org/10.1107/S1600536808022575
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author Copolovici, Dana
Silvestru, Cristian
Isaia, Francesco
Varga, Richard A.
author_facet Copolovici, Dana
Silvestru, Cristian
Isaia, Francesco
Varga, Richard A.
author_sort Copolovici, Dana
collection PubMed
description The title compound, [Pd(2)(C(11)H(14)NO)(2)Cl(2)], has a dimeric structure with Cl atoms bridging the two Pd atoms, one half of the mol­ecule being generated by symmetry due to the crystallographic inversion centre located in the middle of the perfectly planar Pd(2)Cl(2) ring. The five-membered ring adopts an envelope conformation, while the morpholino group has a chair conformation. The geometry around the metal centres is distorted square-planar, as a result of a strong intra­molecular N→Pd coordination trans to a Pd—Cl bond. In the crystal structure, the dimeric structure is strengthened by inter­molecular C—H⋯Cl hydrogen bonds. C—H⋯C(phen­yl) inter­actions link the dimers into a columnar supra­molecular array along the a axis; the dimers are further connected by C—H⋯Ph inter­actions into a three-dimensional supra­molecular arrangement.
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spelling pubmed-29619712010-12-30 Di-μ-chlorido-bis­{[2-(morpholinometh­yl)phenyl-κ(2) C (1),N]palladium(II)} Copolovici, Dana Silvestru, Cristian Isaia, Francesco Varga, Richard A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pd(2)(C(11)H(14)NO)(2)Cl(2)], has a dimeric structure with Cl atoms bridging the two Pd atoms, one half of the mol­ecule being generated by symmetry due to the crystallographic inversion centre located in the middle of the perfectly planar Pd(2)Cl(2) ring. The five-membered ring adopts an envelope conformation, while the morpholino group has a chair conformation. The geometry around the metal centres is distorted square-planar, as a result of a strong intra­molecular N→Pd coordination trans to a Pd—Cl bond. In the crystal structure, the dimeric structure is strengthened by inter­molecular C—H⋯Cl hydrogen bonds. C—H⋯C(phen­yl) inter­actions link the dimers into a columnar supra­molecular array along the a axis; the dimers are further connected by C—H⋯Ph inter­actions into a three-dimensional supra­molecular arrangement. International Union of Crystallography 2008-07-23 /pmc/articles/PMC2961971/ /pubmed/21203041 http://dx.doi.org/10.1107/S1600536808022575 Text en © Copolovici et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Copolovici, Dana
Silvestru, Cristian
Isaia, Francesco
Varga, Richard A.
Di-μ-chlorido-bis­{[2-(morpholinometh­yl)phenyl-κ(2) C (1),N]palladium(II)}
title Di-μ-chlorido-bis­{[2-(morpholinometh­yl)phenyl-κ(2) C (1),N]palladium(II)}
title_full Di-μ-chlorido-bis­{[2-(morpholinometh­yl)phenyl-κ(2) C (1),N]palladium(II)}
title_fullStr Di-μ-chlorido-bis­{[2-(morpholinometh­yl)phenyl-κ(2) C (1),N]palladium(II)}
title_full_unstemmed Di-μ-chlorido-bis­{[2-(morpholinometh­yl)phenyl-κ(2) C (1),N]palladium(II)}
title_short Di-μ-chlorido-bis­{[2-(morpholinometh­yl)phenyl-κ(2) C (1),N]palladium(II)}
title_sort di-μ-chlorido-bis­{[2-(morpholinometh­yl)phenyl-κ(2) c (1),n]palladium(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961971/
https://www.ncbi.nlm.nih.gov/pubmed/21203041
http://dx.doi.org/10.1107/S1600536808022575
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