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Di-μ-chlorido-bis{[2-(morpholinomethyl)phenyl-κ(2) C (1),N]palladium(II)}
The title compound, [Pd(2)(C(11)H(14)NO)(2)Cl(2)], has a dimeric structure with Cl atoms bridging the two Pd atoms, one half of the molecule being generated by symmetry due to the crystallographic inversion centre located in the middle of the perfectly planar Pd(2)Cl(2) ring. The five-membered ring...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961971/ https://www.ncbi.nlm.nih.gov/pubmed/21203041 http://dx.doi.org/10.1107/S1600536808022575 |
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author | Copolovici, Dana Silvestru, Cristian Isaia, Francesco Varga, Richard A. |
author_facet | Copolovici, Dana Silvestru, Cristian Isaia, Francesco Varga, Richard A. |
author_sort | Copolovici, Dana |
collection | PubMed |
description | The title compound, [Pd(2)(C(11)H(14)NO)(2)Cl(2)], has a dimeric structure with Cl atoms bridging the two Pd atoms, one half of the molecule being generated by symmetry due to the crystallographic inversion centre located in the middle of the perfectly planar Pd(2)Cl(2) ring. The five-membered ring adopts an envelope conformation, while the morpholino group has a chair conformation. The geometry around the metal centres is distorted square-planar, as a result of a strong intramolecular N→Pd coordination trans to a Pd—Cl bond. In the crystal structure, the dimeric structure is strengthened by intermolecular C—H⋯Cl hydrogen bonds. C—H⋯C(phenyl) interactions link the dimers into a columnar supramolecular array along the a axis; the dimers are further connected by C—H⋯Ph interactions into a three-dimensional supramolecular arrangement. |
format | Text |
id | pubmed-2961971 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29619712010-12-30 Di-μ-chlorido-bis{[2-(morpholinomethyl)phenyl-κ(2) C (1),N]palladium(II)} Copolovici, Dana Silvestru, Cristian Isaia, Francesco Varga, Richard A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pd(2)(C(11)H(14)NO)(2)Cl(2)], has a dimeric structure with Cl atoms bridging the two Pd atoms, one half of the molecule being generated by symmetry due to the crystallographic inversion centre located in the middle of the perfectly planar Pd(2)Cl(2) ring. The five-membered ring adopts an envelope conformation, while the morpholino group has a chair conformation. The geometry around the metal centres is distorted square-planar, as a result of a strong intramolecular N→Pd coordination trans to a Pd—Cl bond. In the crystal structure, the dimeric structure is strengthened by intermolecular C—H⋯Cl hydrogen bonds. C—H⋯C(phenyl) interactions link the dimers into a columnar supramolecular array along the a axis; the dimers are further connected by C—H⋯Ph interactions into a three-dimensional supramolecular arrangement. International Union of Crystallography 2008-07-23 /pmc/articles/PMC2961971/ /pubmed/21203041 http://dx.doi.org/10.1107/S1600536808022575 Text en © Copolovici et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Copolovici, Dana Silvestru, Cristian Isaia, Francesco Varga, Richard A. Di-μ-chlorido-bis{[2-(morpholinomethyl)phenyl-κ(2) C (1),N]palladium(II)} |
title | Di-μ-chlorido-bis{[2-(morpholinomethyl)phenyl-κ(2)
C
(1),N]palladium(II)} |
title_full | Di-μ-chlorido-bis{[2-(morpholinomethyl)phenyl-κ(2)
C
(1),N]palladium(II)} |
title_fullStr | Di-μ-chlorido-bis{[2-(morpholinomethyl)phenyl-κ(2)
C
(1),N]palladium(II)} |
title_full_unstemmed | Di-μ-chlorido-bis{[2-(morpholinomethyl)phenyl-κ(2)
C
(1),N]palladium(II)} |
title_short | Di-μ-chlorido-bis{[2-(morpholinomethyl)phenyl-κ(2)
C
(1),N]palladium(II)} |
title_sort | di-μ-chlorido-bis{[2-(morpholinomethyl)phenyl-κ(2)
c
(1),n]palladium(ii)} |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961971/ https://www.ncbi.nlm.nih.gov/pubmed/21203041 http://dx.doi.org/10.1107/S1600536808022575 |
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