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Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyloxymethyl)tetrazolato-κ(4) N (1),O,N (5):N (4)]manganese(II)]
In the structure of the title compound, [Mn(C(11)H(8)N(5)O)(N(3))](n), the Mn atoms are hexacoordinated by five N atoms and one O atom. The coordination polyhedron of the Mn atom is a slightly distorted octahedron. The Mn atoms are connected by azide anions with a μ(2)-1,1 mode and by 5-(8-quinoly...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961973/ https://www.ncbi.nlm.nih.gov/pubmed/21203043 http://dx.doi.org/10.1107/S1600536808022617 |
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author | Chen, Fang Ye, Heng-Yun |
author_facet | Chen, Fang Ye, Heng-Yun |
author_sort | Chen, Fang |
collection | PubMed |
description | In the structure of the title compound, [Mn(C(11)H(8)N(5)O)(N(3))](n), the Mn atoms are hexacoordinated by five N atoms and one O atom. The coordination polyhedron of the Mn atom is a slightly distorted octahedron. The Mn atoms are connected by azide anions with a μ(2)-1,1 mode and by 5-(8-quinolyloxymethyl)tetrazolate ligands in a μ(2)-η(1)(N),η(3)-(N,N,O) fashion to form a two-dimensional framework parallel to the (100) plane. Geometric parameters of the organic ligand are in the normal ranges and the dihedral angle between the quinoline ring system and the tetrazole unit is 7.41 (15)°. The structure involves intra- and intermolecular C—H⋯N hydrogen bonds. |
format | Text |
id | pubmed-2961973 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29619732010-12-30 Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyloxymethyl)tetrazolato-κ(4) N (1),O,N (5):N (4)]manganese(II)] Chen, Fang Ye, Heng-Yun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [Mn(C(11)H(8)N(5)O)(N(3))](n), the Mn atoms are hexacoordinated by five N atoms and one O atom. The coordination polyhedron of the Mn atom is a slightly distorted octahedron. The Mn atoms are connected by azide anions with a μ(2)-1,1 mode and by 5-(8-quinolyloxymethyl)tetrazolate ligands in a μ(2)-η(1)(N),η(3)-(N,N,O) fashion to form a two-dimensional framework parallel to the (100) plane. Geometric parameters of the organic ligand are in the normal ranges and the dihedral angle between the quinoline ring system and the tetrazole unit is 7.41 (15)°. The structure involves intra- and intermolecular C—H⋯N hydrogen bonds. International Union of Crystallography 2008-07-23 /pmc/articles/PMC2961973/ /pubmed/21203043 http://dx.doi.org/10.1107/S1600536808022617 Text en © Chen and Ye 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Chen, Fang Ye, Heng-Yun Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyloxymethyl)tetrazolato-κ(4) N (1),O,N (5):N (4)]manganese(II)] |
title | Poly[(μ(2)-azido-κ(2)
N
(1):N
(1))[μ(2)-5-(8-quinolyloxymethyl)tetrazolato-κ(4)
N
(1),O,N
(5):N
(4)]manganese(II)] |
title_full | Poly[(μ(2)-azido-κ(2)
N
(1):N
(1))[μ(2)-5-(8-quinolyloxymethyl)tetrazolato-κ(4)
N
(1),O,N
(5):N
(4)]manganese(II)] |
title_fullStr | Poly[(μ(2)-azido-κ(2)
N
(1):N
(1))[μ(2)-5-(8-quinolyloxymethyl)tetrazolato-κ(4)
N
(1),O,N
(5):N
(4)]manganese(II)] |
title_full_unstemmed | Poly[(μ(2)-azido-κ(2)
N
(1):N
(1))[μ(2)-5-(8-quinolyloxymethyl)tetrazolato-κ(4)
N
(1),O,N
(5):N
(4)]manganese(II)] |
title_short | Poly[(μ(2)-azido-κ(2)
N
(1):N
(1))[μ(2)-5-(8-quinolyloxymethyl)tetrazolato-κ(4)
N
(1),O,N
(5):N
(4)]manganese(II)] |
title_sort | poly[(μ(2)-azido-κ(2)
n
(1):n
(1))[μ(2)-5-(8-quinolyloxymethyl)tetrazolato-κ(4)
n
(1),o,n
(5):n
(4)]manganese(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961973/ https://www.ncbi.nlm.nih.gov/pubmed/21203043 http://dx.doi.org/10.1107/S1600536808022617 |
work_keys_str_mv | AT chenfang polym2azidok2n1n1m258quinolyloxymethyltetrazolatok4n1on5n4manganeseii AT yehengyun polym2azidok2n1n1m258quinolyloxymethyltetrazolatok4n1on5n4manganeseii |