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Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyloxymeth­yl)tetra­zolato-κ(4) N (1),O,N (5):N (4)]manganese(II)]

In the structure of the title compound, [Mn(C(11)H(8)N(5)O)(N(3))](n), the Mn atoms are hexa­coordinated by five N atoms and one O atom. The coordination polyhedron of the Mn atom is a slightly distorted octa­hedron. The Mn atoms are connected by azide anions with a μ(2)-1,1 mode and by 5-(8-quinoly...

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Detalles Bibliográficos
Autores principales: Chen, Fang, Ye, Heng-Yun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961973/
https://www.ncbi.nlm.nih.gov/pubmed/21203043
http://dx.doi.org/10.1107/S1600536808022617
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author Chen, Fang
Ye, Heng-Yun
author_facet Chen, Fang
Ye, Heng-Yun
author_sort Chen, Fang
collection PubMed
description In the structure of the title compound, [Mn(C(11)H(8)N(5)O)(N(3))](n), the Mn atoms are hexa­coordinated by five N atoms and one O atom. The coordination polyhedron of the Mn atom is a slightly distorted octa­hedron. The Mn atoms are connected by azide anions with a μ(2)-1,1 mode and by 5-(8-quinolyloxymeth­yl)tetra­zolate ligands in a μ(2)-η(1)(N),η(3)-(N,N,O) fashion to form a two-dimensional framework parallel to the (100) plane. Geometric parameters of the organic ligand are in the normal ranges and the dihedral angle between the quinoline ring system and the tetra­zole unit is 7.41 (15)°. The structure involves intra- and inter­molecular C—H⋯N hydrogen bonds.
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spelling pubmed-29619732010-12-30 Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyloxymeth­yl)tetra­zolato-κ(4) N (1),O,N (5):N (4)]manganese(II)] Chen, Fang Ye, Heng-Yun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [Mn(C(11)H(8)N(5)O)(N(3))](n), the Mn atoms are hexa­coordinated by five N atoms and one O atom. The coordination polyhedron of the Mn atom is a slightly distorted octa­hedron. The Mn atoms are connected by azide anions with a μ(2)-1,1 mode and by 5-(8-quinolyloxymeth­yl)tetra­zolate ligands in a μ(2)-η(1)(N),η(3)-(N,N,O) fashion to form a two-dimensional framework parallel to the (100) plane. Geometric parameters of the organic ligand are in the normal ranges and the dihedral angle between the quinoline ring system and the tetra­zole unit is 7.41 (15)°. The structure involves intra- and inter­molecular C—H⋯N hydrogen bonds. International Union of Crystallography 2008-07-23 /pmc/articles/PMC2961973/ /pubmed/21203043 http://dx.doi.org/10.1107/S1600536808022617 Text en © Chen and Ye 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Fang
Ye, Heng-Yun
Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyloxymeth­yl)tetra­zolato-κ(4) N (1),O,N (5):N (4)]manganese(II)]
title Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyloxymeth­yl)tetra­zolato-κ(4) N (1),O,N (5):N (4)]manganese(II)]
title_full Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyloxymeth­yl)tetra­zolato-κ(4) N (1),O,N (5):N (4)]manganese(II)]
title_fullStr Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyloxymeth­yl)tetra­zolato-κ(4) N (1),O,N (5):N (4)]manganese(II)]
title_full_unstemmed Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyloxymeth­yl)tetra­zolato-κ(4) N (1),O,N (5):N (4)]manganese(II)]
title_short Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyloxymeth­yl)tetra­zolato-κ(4) N (1),O,N (5):N (4)]manganese(II)]
title_sort poly[(μ(2)-azido-κ(2) n (1):n (1))[μ(2)-5-(8-quinolyloxymeth­yl)tetra­zolato-κ(4) n (1),o,n (5):n (4)]manganese(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961973/
https://www.ncbi.nlm.nih.gov/pubmed/21203043
http://dx.doi.org/10.1107/S1600536808022617
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