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cis-Aquabis(2,4-dichloro-6-formylphenolato-κ(2) O,O′)(N,N-dimethylformamide-κO)nickel(II)
In the title compound, [Ni(C(7)H(3)Cl(2)O(2))(2)(C(3)H(7)NO)(H(2)O)], the Ni(II) ion is coordinated by four O atoms from two bidentate 2,4-dichloro-6-formylphenolate ligands, one O atom from a water ligand and one O atom from a dimethylformamide ligand in a slightly distorted octahedral environme...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961979/ https://www.ncbi.nlm.nih.gov/pubmed/21203049 http://dx.doi.org/10.1107/S1600536808022939 |
| _version_ | 1782189111835099136 |
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| author | Chen, Fa-Yun Zhang, Shu-Hua Ge, Chen-Min |
| author_facet | Chen, Fa-Yun Zhang, Shu-Hua Ge, Chen-Min |
| author_sort | Chen, Fa-Yun |
| collection | PubMed |
| description | In the title compound, [Ni(C(7)H(3)Cl(2)O(2))(2)(C(3)H(7)NO)(H(2)O)], the Ni(II) ion is coordinated by four O atoms from two bidentate 2,4-dichloro-6-formylphenolate ligands, one O atom from a water ligand and one O atom from a dimethylformamide ligand in a slightly distorted octahedral environment. In the crystal structure, centrosymmetric dimers are formed though O—H⋯O and O—H⋯Cl hydrogen bonds; π–π stacking interactions, with a centroid–centroid distance of 3.796 (2) Å, are also found. |
| format | Text |
| id | pubmed-2961979 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29619792010-12-30 cis-Aquabis(2,4-dichloro-6-formylphenolato-κ(2) O,O′)(N,N-dimethylformamide-κO)nickel(II) Chen, Fa-Yun Zhang, Shu-Hua Ge, Chen-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(7)H(3)Cl(2)O(2))(2)(C(3)H(7)NO)(H(2)O)], the Ni(II) ion is coordinated by four O atoms from two bidentate 2,4-dichloro-6-formylphenolate ligands, one O atom from a water ligand and one O atom from a dimethylformamide ligand in a slightly distorted octahedral environment. In the crystal structure, centrosymmetric dimers are formed though O—H⋯O and O—H⋯Cl hydrogen bonds; π–π stacking interactions, with a centroid–centroid distance of 3.796 (2) Å, are also found. International Union of Crystallography 2008-07-26 /pmc/articles/PMC2961979/ /pubmed/21203049 http://dx.doi.org/10.1107/S1600536808022939 Text en © Chen et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chen, Fa-Yun Zhang, Shu-Hua Ge, Chen-Min cis-Aquabis(2,4-dichloro-6-formylphenolato-κ(2) O,O′)(N,N-dimethylformamide-κO)nickel(II) |
| title |
cis-Aquabis(2,4-dichloro-6-formylphenolato-κ(2)
O,O′)(N,N-dimethylformamide-κO)nickel(II) |
| title_full |
cis-Aquabis(2,4-dichloro-6-formylphenolato-κ(2)
O,O′)(N,N-dimethylformamide-κO)nickel(II) |
| title_fullStr |
cis-Aquabis(2,4-dichloro-6-formylphenolato-κ(2)
O,O′)(N,N-dimethylformamide-κO)nickel(II) |
| title_full_unstemmed |
cis-Aquabis(2,4-dichloro-6-formylphenolato-κ(2)
O,O′)(N,N-dimethylformamide-κO)nickel(II) |
| title_short |
cis-Aquabis(2,4-dichloro-6-formylphenolato-κ(2)
O,O′)(N,N-dimethylformamide-κO)nickel(II) |
| title_sort | cis-aquabis(2,4-dichloro-6-formylphenolato-κ(2)
o,o′)(n,n-dimethylformamide-κo)nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961979/ https://www.ncbi.nlm.nih.gov/pubmed/21203049 http://dx.doi.org/10.1107/S1600536808022939 |
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