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Bis[μ-1,2-bis(1H-imidazol-1-ylmethyl)benzene-κ(2) N (3):N (3′)]disilver(I) bis(4-amino-2,5-dichlorobenzenesulfonate) tetrahydrate
The asymmetric unit of the title compound, [Ag(2)(C(14)H(14)N(4))(2)](C(6)H(4)Cl(2)NO(3)S)(2)·4H(2)O, contains one-half of each of two independent dicationic units, two 4-amino-2,5-dichlorobenzenesulfonate anions and four water molecules. Each centrosymmetric dicationic unit has a dinuclear struc...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961981/ https://www.ncbi.nlm.nih.gov/pubmed/21203051 http://dx.doi.org/10.1107/S1600536808023052 |
Sumario: | The asymmetric unit of the title compound, [Ag(2)(C(14)H(14)N(4))(2)](C(6)H(4)Cl(2)NO(3)S)(2)·4H(2)O, contains one-half of each of two independent dicationic units, two 4-amino-2,5-dichlorobenzenesulfonate anions and four water molecules. Each centrosymmetric dicationic unit has a dinuclear structure in which two Ag(I) atoms are bridged by two 1,2-bis(1H-imidazol-1-ylmethyl)benzene ligands in a slightly distorted linear coordination geometry. The 4-amino-2,5-dichlorobenzenesulfonate anion does not coordinate with the Ag(I) center, acting only as a counteranion. In the crystal structure, intermolecular O—H⋯O and N—H⋯O hydrogen bonds form a three-dimensional network. |
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