Cargando…

catena-Poly[manganese(II)-(μ(2)-3,5-di-2-pyridyl-1,2,4-triazol­ato)-μ(2)-formato]

Owing to the presence of crystallographic twofold rotation axes (site symmetry 2, Wyckoff letters e and f), the asymmetric unit of the title compound, [Mn(C(12)H(8)N(5))(CHO(2))](n), contains one-half of an Mn(II) cation, one-half of a bpt anion (Hbpt is 3,5-di-2-pyridyl-4H-1,2,4-triazole) and one-h...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Ya-Wen, Zhang, Gong, Sun, Yan-Yan, Cheng, Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961983/
https://www.ncbi.nlm.nih.gov/pubmed/21203053
http://dx.doi.org/10.1107/S160053680802299X
_version_ 1782189112779866112
author Zhang, Ya-Wen
Zhang, Gong
Sun, Yan-Yan
Cheng, Lin
author_facet Zhang, Ya-Wen
Zhang, Gong
Sun, Yan-Yan
Cheng, Lin
author_sort Zhang, Ya-Wen
collection PubMed
description Owing to the presence of crystallographic twofold rotation axes (site symmetry 2, Wyckoff letters e and f), the asymmetric unit of the title compound, [Mn(C(12)H(8)N(5))(CHO(2))](n), contains one-half of an Mn(II) cation, one-half of a bpt anion (Hbpt is 3,5-di-2-pyridyl-4H-1,2,4-triazole) and one-half of a formate anion. The bpt and formate ligands occupy the same C (2) symmetry, while the Mn(II) ion resides on another crystallographic twofold rotation axis. Each bpt ligand acts as a cis-bis-chelate to ligate two Mn(II) ions into a one-dimensional chain running along the crystallographic 4(1) screw axis. Adjacent Mn(II) ions are further bridged by a μ(2)-formate ligand, completing the distorted octa­hedral coordination geometry of the cation.
format Text
id pubmed-2961983
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29619832010-12-30 catena-Poly[manganese(II)-(μ(2)-3,5-di-2-pyridyl-1,2,4-triazol­ato)-μ(2)-formato] Zhang, Ya-Wen Zhang, Gong Sun, Yan-Yan Cheng, Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Owing to the presence of crystallographic twofold rotation axes (site symmetry 2, Wyckoff letters e and f), the asymmetric unit of the title compound, [Mn(C(12)H(8)N(5))(CHO(2))](n), contains one-half of an Mn(II) cation, one-half of a bpt anion (Hbpt is 3,5-di-2-pyridyl-4H-1,2,4-triazole) and one-half of a formate anion. The bpt and formate ligands occupy the same C (2) symmetry, while the Mn(II) ion resides on another crystallographic twofold rotation axis. Each bpt ligand acts as a cis-bis-chelate to ligate two Mn(II) ions into a one-dimensional chain running along the crystallographic 4(1) screw axis. Adjacent Mn(II) ions are further bridged by a μ(2)-formate ligand, completing the distorted octa­hedral coordination geometry of the cation. International Union of Crystallography 2008-07-26 /pmc/articles/PMC2961983/ /pubmed/21203053 http://dx.doi.org/10.1107/S160053680802299X Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Ya-Wen
Zhang, Gong
Sun, Yan-Yan
Cheng, Lin
catena-Poly[manganese(II)-(μ(2)-3,5-di-2-pyridyl-1,2,4-triazol­ato)-μ(2)-formato]
title catena-Poly[manganese(II)-(μ(2)-3,5-di-2-pyridyl-1,2,4-triazol­ato)-μ(2)-formato]
title_full catena-Poly[manganese(II)-(μ(2)-3,5-di-2-pyridyl-1,2,4-triazol­ato)-μ(2)-formato]
title_fullStr catena-Poly[manganese(II)-(μ(2)-3,5-di-2-pyridyl-1,2,4-triazol­ato)-μ(2)-formato]
title_full_unstemmed catena-Poly[manganese(II)-(μ(2)-3,5-di-2-pyridyl-1,2,4-triazol­ato)-μ(2)-formato]
title_short catena-Poly[manganese(II)-(μ(2)-3,5-di-2-pyridyl-1,2,4-triazol­ato)-μ(2)-formato]
title_sort catena-poly[manganese(ii)-(μ(2)-3,5-di-2-pyridyl-1,2,4-triazol­ato)-μ(2)-formato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961983/
https://www.ncbi.nlm.nih.gov/pubmed/21203053
http://dx.doi.org/10.1107/S160053680802299X
work_keys_str_mv AT zhangyawen catenapolymanganeseiim235di2pyridyl124triazolatom2formato
AT zhanggong catenapolymanganeseiim235di2pyridyl124triazolatom2formato
AT sunyanyan catenapolymanganeseiim235di2pyridyl124triazolatom2formato
AT chenglin catenapolymanganeseiim235di2pyridyl124triazolatom2formato