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catena-Poly[manganese(II)-(μ(2)-3,5-di-2-pyridyl-1,2,4-triazolato)-μ(2)-formato]
Owing to the presence of crystallographic twofold rotation axes (site symmetry 2, Wyckoff letters e and f), the asymmetric unit of the title compound, [Mn(C(12)H(8)N(5))(CHO(2))](n), contains one-half of an Mn(II) cation, one-half of a bpt anion (Hbpt is 3,5-di-2-pyridyl-4H-1,2,4-triazole) and one-h...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961983/ https://www.ncbi.nlm.nih.gov/pubmed/21203053 http://dx.doi.org/10.1107/S160053680802299X |
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author | Zhang, Ya-Wen Zhang, Gong Sun, Yan-Yan Cheng, Lin |
author_facet | Zhang, Ya-Wen Zhang, Gong Sun, Yan-Yan Cheng, Lin |
author_sort | Zhang, Ya-Wen |
collection | PubMed |
description | Owing to the presence of crystallographic twofold rotation axes (site symmetry 2, Wyckoff letters e and f), the asymmetric unit of the title compound, [Mn(C(12)H(8)N(5))(CHO(2))](n), contains one-half of an Mn(II) cation, one-half of a bpt anion (Hbpt is 3,5-di-2-pyridyl-4H-1,2,4-triazole) and one-half of a formate anion. The bpt and formate ligands occupy the same C (2) symmetry, while the Mn(II) ion resides on another crystallographic twofold rotation axis. Each bpt ligand acts as a cis-bis-chelate to ligate two Mn(II) ions into a one-dimensional chain running along the crystallographic 4(1) screw axis. Adjacent Mn(II) ions are further bridged by a μ(2)-formate ligand, completing the distorted octahedral coordination geometry of the cation. |
format | Text |
id | pubmed-2961983 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29619832010-12-30 catena-Poly[manganese(II)-(μ(2)-3,5-di-2-pyridyl-1,2,4-triazolato)-μ(2)-formato] Zhang, Ya-Wen Zhang, Gong Sun, Yan-Yan Cheng, Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Owing to the presence of crystallographic twofold rotation axes (site symmetry 2, Wyckoff letters e and f), the asymmetric unit of the title compound, [Mn(C(12)H(8)N(5))(CHO(2))](n), contains one-half of an Mn(II) cation, one-half of a bpt anion (Hbpt is 3,5-di-2-pyridyl-4H-1,2,4-triazole) and one-half of a formate anion. The bpt and formate ligands occupy the same C (2) symmetry, while the Mn(II) ion resides on another crystallographic twofold rotation axis. Each bpt ligand acts as a cis-bis-chelate to ligate two Mn(II) ions into a one-dimensional chain running along the crystallographic 4(1) screw axis. Adjacent Mn(II) ions are further bridged by a μ(2)-formate ligand, completing the distorted octahedral coordination geometry of the cation. International Union of Crystallography 2008-07-26 /pmc/articles/PMC2961983/ /pubmed/21203053 http://dx.doi.org/10.1107/S160053680802299X Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Ya-Wen Zhang, Gong Sun, Yan-Yan Cheng, Lin catena-Poly[manganese(II)-(μ(2)-3,5-di-2-pyridyl-1,2,4-triazolato)-μ(2)-formato] |
title |
catena-Poly[manganese(II)-(μ(2)-3,5-di-2-pyridyl-1,2,4-triazolato)-μ(2)-formato] |
title_full |
catena-Poly[manganese(II)-(μ(2)-3,5-di-2-pyridyl-1,2,4-triazolato)-μ(2)-formato] |
title_fullStr |
catena-Poly[manganese(II)-(μ(2)-3,5-di-2-pyridyl-1,2,4-triazolato)-μ(2)-formato] |
title_full_unstemmed |
catena-Poly[manganese(II)-(μ(2)-3,5-di-2-pyridyl-1,2,4-triazolato)-μ(2)-formato] |
title_short |
catena-Poly[manganese(II)-(μ(2)-3,5-di-2-pyridyl-1,2,4-triazolato)-μ(2)-formato] |
title_sort | catena-poly[manganese(ii)-(μ(2)-3,5-di-2-pyridyl-1,2,4-triazolato)-μ(2)-formato] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961983/ https://www.ncbi.nlm.nih.gov/pubmed/21203053 http://dx.doi.org/10.1107/S160053680802299X |
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