Poly[[diaqua­bis(μ(3)-maleato-κ(4) O (1):O (1′),O (4):O(4′))dicopper(II)] trihydrate]

In the title compound, {[Cu(2)(C(4)H(2)O(4))(2)(H(2)O)(2)]·3H(2)O}(n), Cu(II) ions with square-pyramidal coordination are bridged by exo­tri­dentate maleate dianions into [Cu(2)(maleate)(2)(H(2)O)(2)](n) layers coincident with the bc crystal plane. The inter­lamellar regions contain hydrogen-bonded...

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Detalles Bibliográficos
Autores principales: Farnum, Gregory A., LaDuca, Robert L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961984/
https://www.ncbi.nlm.nih.gov/pubmed/21203054
http://dx.doi.org/10.1107/S1600536808023131
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author Farnum, Gregory A.
LaDuca, Robert L.
author_facet Farnum, Gregory A.
LaDuca, Robert L.
author_sort Farnum, Gregory A.
collection PubMed
description In the title compound, {[Cu(2)(C(4)H(2)O(4))(2)(H(2)O)(2)]·3H(2)O}(n), Cu(II) ions with square-pyramidal coordination are bridged by exo­tri­dentate maleate dianions into [Cu(2)(maleate)(2)(H(2)O)(2)](n) layers coincident with the bc crystal plane. The inter­lamellar regions contain hydrogen-bonded cyclic water hexa­mers which facilitate layer stacking into a pseudo-three-dimensional crystal structure. The water hexamers themselves are formed by the operation of crystallographic inversion centers on sets of three crystallographically distinct water molecules of hydration.
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spelling pubmed-29619842010-12-30 Poly[[diaqua­bis(μ(3)-maleato-κ(4) O (1):O (1′),O (4):O(4′))dicopper(II)] trihydrate] Farnum, Gregory A. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cu(2)(C(4)H(2)O(4))(2)(H(2)O)(2)]·3H(2)O}(n), Cu(II) ions with square-pyramidal coordination are bridged by exo­tri­dentate maleate dianions into [Cu(2)(maleate)(2)(H(2)O)(2)](n) layers coincident with the bc crystal plane. The inter­lamellar regions contain hydrogen-bonded cyclic water hexa­mers which facilitate layer stacking into a pseudo-three-dimensional crystal structure. The water hexamers themselves are formed by the operation of crystallographic inversion centers on sets of three crystallographically distinct water molecules of hydration. International Union of Crystallography 2008-07-26 /pmc/articles/PMC2961984/ /pubmed/21203054 http://dx.doi.org/10.1107/S1600536808023131 Text en © Farnum and LaDuca 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Farnum, Gregory A.
LaDuca, Robert L.
Poly[[diaqua­bis(μ(3)-maleato-κ(4) O (1):O (1′),O (4):O(4′))dicopper(II)] trihydrate]
title Poly[[diaqua­bis(μ(3)-maleato-κ(4) O (1):O (1′),O (4):O(4′))dicopper(II)] trihydrate]
title_full Poly[[diaqua­bis(μ(3)-maleato-κ(4) O (1):O (1′),O (4):O(4′))dicopper(II)] trihydrate]
title_fullStr Poly[[diaqua­bis(μ(3)-maleato-κ(4) O (1):O (1′),O (4):O(4′))dicopper(II)] trihydrate]
title_full_unstemmed Poly[[diaqua­bis(μ(3)-maleato-κ(4) O (1):O (1′),O (4):O(4′))dicopper(II)] trihydrate]
title_short Poly[[diaqua­bis(μ(3)-maleato-κ(4) O (1):O (1′),O (4):O(4′))dicopper(II)] trihydrate]
title_sort poly[[diaqua­bis(μ(3)-maleato-κ(4) o (1):o (1′),o (4):o(4′))dicopper(ii)] trihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961984/
https://www.ncbi.nlm.nih.gov/pubmed/21203054
http://dx.doi.org/10.1107/S1600536808023131
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