catena-Poly[{μ-cyanido-bis­[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(I)]}-μ-cyanido-copper(I)-μ-cyanido]

In the title compound, [Cu(3)(CN)(3)(C(12)H(12)N(2))(2)], two 2,2′-bipyridine N,N′-chelated Cu(I) atoms are linked by a cyanide bridge that lies about a center of inversion; the Cu(I) atom exists in a tetra­hedral coordination geometry. This dinuclear entity is linked to another Cu(I) atom that lies...

Descripción completa

Detalles Bibliográficos
Autores principales: Lin, Shi-Hong, Yang, Ying-Yi, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961986/
https://www.ncbi.nlm.nih.gov/pubmed/21203056
http://dx.doi.org/10.1107/S1600536808022964
Descripción
Sumario:In the title compound, [Cu(3)(CN)(3)(C(12)H(12)N(2))(2)], two 2,2′-bipyridine N,N′-chelated Cu(I) atoms are linked by a cyanide bridge that lies about a center of inversion; the Cu(I) atom exists in a tetra­hedral coordination geometry. This dinuclear entity is linked to another Cu(I) atom that lies on a twofold rotation axis by another cyanide bridge, these bridges giving rise to the formation of a linear chain motif.

Ejemplares similares