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catena-Poly[{μ-cyanido-bis[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(I)]}-μ-cyanido-copper(I)-μ-cyanido]
In the title compound, [Cu(3)(CN)(3)(C(12)H(12)N(2))(2)], two 2,2′-bipyridine N,N′-chelated Cu(I) atoms are linked by a cyanide bridge that lies about a center of inversion; the Cu(I) atom exists in a tetrahedral coordination geometry. This dinuclear entity is linked to another Cu(I) atom that lies...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961986/ https://www.ncbi.nlm.nih.gov/pubmed/21203056 http://dx.doi.org/10.1107/S1600536808022964 |
| _version_ | 1782189113525403648 |
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| author | Lin, Shi-Hong Yang, Ying-Yi Ng, Seik Weng |
| author_facet | Lin, Shi-Hong Yang, Ying-Yi Ng, Seik Weng |
| author_sort | Lin, Shi-Hong |
| collection | PubMed |
| description | In the title compound, [Cu(3)(CN)(3)(C(12)H(12)N(2))(2)], two 2,2′-bipyridine N,N′-chelated Cu(I) atoms are linked by a cyanide bridge that lies about a center of inversion; the Cu(I) atom exists in a tetrahedral coordination geometry. This dinuclear entity is linked to another Cu(I) atom that lies on a twofold rotation axis by another cyanide bridge, these bridges giving rise to the formation of a linear chain motif. |
| format | Text |
| id | pubmed-2961986 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29619862010-12-30 catena-Poly[{μ-cyanido-bis[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(I)]}-μ-cyanido-copper(I)-μ-cyanido] Lin, Shi-Hong Yang, Ying-Yi Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(3)(CN)(3)(C(12)H(12)N(2))(2)], two 2,2′-bipyridine N,N′-chelated Cu(I) atoms are linked by a cyanide bridge that lies about a center of inversion; the Cu(I) atom exists in a tetrahedral coordination geometry. This dinuclear entity is linked to another Cu(I) atom that lies on a twofold rotation axis by another cyanide bridge, these bridges giving rise to the formation of a linear chain motif. International Union of Crystallography 2008-07-26 /pmc/articles/PMC2961986/ /pubmed/21203056 http://dx.doi.org/10.1107/S1600536808022964 Text en © Lin et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lin, Shi-Hong Yang, Ying-Yi Ng, Seik Weng catena-Poly[{μ-cyanido-bis[(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(I)]}-μ-cyanido-copper(I)-μ-cyanido] |
| title |
catena-Poly[{μ-cyanido-bis[(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)copper(I)]}-μ-cyanido-copper(I)-μ-cyanido] |
| title_full |
catena-Poly[{μ-cyanido-bis[(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)copper(I)]}-μ-cyanido-copper(I)-μ-cyanido] |
| title_fullStr |
catena-Poly[{μ-cyanido-bis[(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)copper(I)]}-μ-cyanido-copper(I)-μ-cyanido] |
| title_full_unstemmed |
catena-Poly[{μ-cyanido-bis[(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)copper(I)]}-μ-cyanido-copper(I)-μ-cyanido] |
| title_short |
catena-Poly[{μ-cyanido-bis[(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)copper(I)]}-μ-cyanido-copper(I)-μ-cyanido] |
| title_sort | catena-poly[{μ-cyanido-bis[(4,4′-dimethyl-2,2′-bipyridine-κ(2)
n,n′)copper(i)]}-μ-cyanido-copper(i)-μ-cyanido] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961986/ https://www.ncbi.nlm.nih.gov/pubmed/21203056 http://dx.doi.org/10.1107/S1600536808022964 |
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