Bis(pentane-2,4-dionato-κ(2) O,O′)bis­[4,4,5,5-tetra­methyl-2-(4-pyridyl)­imidazoline-1-oxyl 3-oxide-κN (2)]manganese(II)

The title compound, [Mn(C(5)H(7)O(2))(2)(C(12)H(16)N(3)O(2))(2)], is isostructural with its Ni(II)-containing analogue [Hao, Mu & Kong (2008 ▶). Acta Cryst. E64, m957]. The asymmetric unit comprises one-half of the mol­ecule and the Mn(II) ion is located on an inversion centre. The coordination...

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Detalles Bibliográficos
Autores principales: Liu, Ying, Zhang, Xianxi, Xue, Zechun, He, Qingpeng, Zhang, Yu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961987/
https://www.ncbi.nlm.nih.gov/pubmed/21203057
http://dx.doi.org/10.1107/S1600536808022952
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author Liu, Ying
Zhang, Xianxi
Xue, Zechun
He, Qingpeng
Zhang, Yu
author_facet Liu, Ying
Zhang, Xianxi
Xue, Zechun
He, Qingpeng
Zhang, Yu
author_sort Liu, Ying
collection PubMed
description The title compound, [Mn(C(5)H(7)O(2))(2)(C(12)H(16)N(3)O(2))(2)], is isostructural with its Ni(II)-containing analogue [Hao, Mu & Kong (2008 ▶). Acta Cryst. E64, m957]. The asymmetric unit comprises one-half of the mol­ecule and the Mn(II) ion is located on an inversion centre. The coordination geometry around the Mn(II) ion is slightly distorted octa­hedral, comprised of four O and two N atoms, in which the four O atoms in the equatorial plane come from two pentane-2,4-dionate ligands and the two N atoms in the axial coordination sites from 4,4,5,5-tetra­methyl-2-(4-pyrid­yl)imidazoline-1-oxyl 3-oxide.
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spelling pubmed-29619872010-12-30 Bis(pentane-2,4-dionato-κ(2) O,O′)bis­[4,4,5,5-tetra­methyl-2-(4-pyridyl)­imidazoline-1-oxyl 3-oxide-κN (2)]manganese(II) Liu, Ying Zhang, Xianxi Xue, Zechun He, Qingpeng Zhang, Yu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mn(C(5)H(7)O(2))(2)(C(12)H(16)N(3)O(2))(2)], is isostructural with its Ni(II)-containing analogue [Hao, Mu & Kong (2008 ▶). Acta Cryst. E64, m957]. The asymmetric unit comprises one-half of the mol­ecule and the Mn(II) ion is located on an inversion centre. The coordination geometry around the Mn(II) ion is slightly distorted octa­hedral, comprised of four O and two N atoms, in which the four O atoms in the equatorial plane come from two pentane-2,4-dionate ligands and the two N atoms in the axial coordination sites from 4,4,5,5-tetra­methyl-2-(4-pyrid­yl)imidazoline-1-oxyl 3-oxide. International Union of Crystallography 2008-07-26 /pmc/articles/PMC2961987/ /pubmed/21203057 http://dx.doi.org/10.1107/S1600536808022952 Text en © Liu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Ying
Zhang, Xianxi
Xue, Zechun
He, Qingpeng
Zhang, Yu
Bis(pentane-2,4-dionato-κ(2) O,O′)bis­[4,4,5,5-tetra­methyl-2-(4-pyridyl)­imidazoline-1-oxyl 3-oxide-κN (2)]manganese(II)
title Bis(pentane-2,4-dionato-κ(2) O,O′)bis­[4,4,5,5-tetra­methyl-2-(4-pyridyl)­imidazoline-1-oxyl 3-oxide-κN (2)]manganese(II)
title_full Bis(pentane-2,4-dionato-κ(2) O,O′)bis­[4,4,5,5-tetra­methyl-2-(4-pyridyl)­imidazoline-1-oxyl 3-oxide-κN (2)]manganese(II)
title_fullStr Bis(pentane-2,4-dionato-κ(2) O,O′)bis­[4,4,5,5-tetra­methyl-2-(4-pyridyl)­imidazoline-1-oxyl 3-oxide-κN (2)]manganese(II)
title_full_unstemmed Bis(pentane-2,4-dionato-κ(2) O,O′)bis­[4,4,5,5-tetra­methyl-2-(4-pyridyl)­imidazoline-1-oxyl 3-oxide-κN (2)]manganese(II)
title_short Bis(pentane-2,4-dionato-κ(2) O,O′)bis­[4,4,5,5-tetra­methyl-2-(4-pyridyl)­imidazoline-1-oxyl 3-oxide-κN (2)]manganese(II)
title_sort bis(pentane-2,4-dionato-κ(2) o,o′)bis­[4,4,5,5-tetra­methyl-2-(4-pyridyl)­imidazoline-1-oxyl 3-oxide-κn (2)]manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961987/
https://www.ncbi.nlm.nih.gov/pubmed/21203057
http://dx.doi.org/10.1107/S1600536808022952
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