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Bis(triphenylguanidinium) tetrachloridocuprate(II)
The structure of the title compound, (C(19)H(18)N(3))(2)[CuCl(4)], consists of square-planar [CuCl(4)](2−) anions and triphenylguanidinium cations. The Cu(II) ion occupies a crystallographic inversion centre. In the cation, the dihedral angles between the phenyl rings and the plane defined by the c...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961991/ https://www.ncbi.nlm.nih.gov/pubmed/21203061 http://dx.doi.org/10.1107/S1600536808023404 |
| _version_ | 1782189114666254336 |
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| author | Pereira Silva, P. S. Martins, N. D. Ramos Silva, M. Matos Beja, A. |
| author_facet | Pereira Silva, P. S. Martins, N. D. Ramos Silva, M. Matos Beja, A. |
| author_sort | Pereira Silva, P. S. |
| collection | PubMed |
| description | The structure of the title compound, (C(19)H(18)N(3))(2)[CuCl(4)], consists of square-planar [CuCl(4)](2−) anions and triphenylguanidinium cations. The Cu(II) ion occupies a crystallographic inversion centre. In the cation, the dihedral angles between the phenyl rings and the plane defined by the central guanidinium fragment are in the range 51.9 (4)–64.4 (3)°. N—H⋯Cl hydrogen bonds assemble the ions into infinite chains running along the b axis. |
| format | Text |
| id | pubmed-2961991 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29619912010-12-30 Bis(triphenylguanidinium) tetrachloridocuprate(II) Pereira Silva, P. S. Martins, N. D. Ramos Silva, M. Matos Beja, A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, (C(19)H(18)N(3))(2)[CuCl(4)], consists of square-planar [CuCl(4)](2−) anions and triphenylguanidinium cations. The Cu(II) ion occupies a crystallographic inversion centre. In the cation, the dihedral angles between the phenyl rings and the plane defined by the central guanidinium fragment are in the range 51.9 (4)–64.4 (3)°. N—H⋯Cl hydrogen bonds assemble the ions into infinite chains running along the b axis. International Union of Crystallography 2008-07-31 /pmc/articles/PMC2961991/ /pubmed/21203061 http://dx.doi.org/10.1107/S1600536808023404 Text en © Pereira Silva et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Pereira Silva, P. S. Martins, N. D. Ramos Silva, M. Matos Beja, A. Bis(triphenylguanidinium) tetrachloridocuprate(II) |
| title | Bis(triphenylguanidinium) tetrachloridocuprate(II) |
| title_full | Bis(triphenylguanidinium) tetrachloridocuprate(II) |
| title_fullStr | Bis(triphenylguanidinium) tetrachloridocuprate(II) |
| title_full_unstemmed | Bis(triphenylguanidinium) tetrachloridocuprate(II) |
| title_short | Bis(triphenylguanidinium) tetrachloridocuprate(II) |
| title_sort | bis(triphenylguanidinium) tetrachloridocuprate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961991/ https://www.ncbi.nlm.nih.gov/pubmed/21203061 http://dx.doi.org/10.1107/S1600536808023404 |
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