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[μ(3)-2,2,4,4,6,6-Hexakis(3,5-dimethyl­pyrazol-1-yl)-2λ(5),4λ(5),6λ(5)-1,3,5,2,4,6-triaza­triphosphinine]tris­[cis-dichloridopalladium(II)]

The title complex, [Pd(3)Cl(6)(C(30)H(42)N(15)P(3))], possesses C (3) mol­ecular symmetry. The P and N atoms of the cyclo­triphosphazene and the Pd atom are located on the crystallographic mirror plane. Each of the three symmetry-related Pd atoms is coordinated by two chloride ligands and two exocyc...

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Detalles Bibliográficos
Autores principales: Yun, Sung Yol, Lee, Soon W.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961992/
https://www.ncbi.nlm.nih.gov/pubmed/21203062
http://dx.doi.org/10.1107/S1600536808023167
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author Yun, Sung Yol
Lee, Soon W.
author_facet Yun, Sung Yol
Lee, Soon W.
author_sort Yun, Sung Yol
collection PubMed
description The title complex, [Pd(3)Cl(6)(C(30)H(42)N(15)P(3))], possesses C (3) mol­ecular symmetry. The P and N atoms of the cyclo­triphosphazene and the Pd atom are located on the crystallographic mirror plane. Each of the three symmetry-related Pd atoms is coordinated by two chloride ligands and two exocyclic pyrazolyl N atoms, but not by the cyclo­triphosphazene N atoms.
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spelling pubmed-29619922010-12-30 [μ(3)-2,2,4,4,6,6-Hexakis(3,5-dimethyl­pyrazol-1-yl)-2λ(5),4λ(5),6λ(5)-1,3,5,2,4,6-triaza­triphosphinine]tris­[cis-dichloridopalladium(II)] Yun, Sung Yol Lee, Soon W. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Pd(3)Cl(6)(C(30)H(42)N(15)P(3))], possesses C (3) mol­ecular symmetry. The P and N atoms of the cyclo­triphosphazene and the Pd atom are located on the crystallographic mirror plane. Each of the three symmetry-related Pd atoms is coordinated by two chloride ligands and two exocyclic pyrazolyl N atoms, but not by the cyclo­triphosphazene N atoms. International Union of Crystallography 2008-07-31 /pmc/articles/PMC2961992/ /pubmed/21203062 http://dx.doi.org/10.1107/S1600536808023167 Text en © Yun and Lee 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yun, Sung Yol
Lee, Soon W.
[μ(3)-2,2,4,4,6,6-Hexakis(3,5-dimethyl­pyrazol-1-yl)-2λ(5),4λ(5),6λ(5)-1,3,5,2,4,6-triaza­triphosphinine]tris­[cis-dichloridopalladium(II)]
title [μ(3)-2,2,4,4,6,6-Hexakis(3,5-dimethyl­pyrazol-1-yl)-2λ(5),4λ(5),6λ(5)-1,3,5,2,4,6-triaza­triphosphinine]tris­[cis-dichloridopalladium(II)]
title_full [μ(3)-2,2,4,4,6,6-Hexakis(3,5-dimethyl­pyrazol-1-yl)-2λ(5),4λ(5),6λ(5)-1,3,5,2,4,6-triaza­triphosphinine]tris­[cis-dichloridopalladium(II)]
title_fullStr [μ(3)-2,2,4,4,6,6-Hexakis(3,5-dimethyl­pyrazol-1-yl)-2λ(5),4λ(5),6λ(5)-1,3,5,2,4,6-triaza­triphosphinine]tris­[cis-dichloridopalladium(II)]
title_full_unstemmed [μ(3)-2,2,4,4,6,6-Hexakis(3,5-dimethyl­pyrazol-1-yl)-2λ(5),4λ(5),6λ(5)-1,3,5,2,4,6-triaza­triphosphinine]tris­[cis-dichloridopalladium(II)]
title_short [μ(3)-2,2,4,4,6,6-Hexakis(3,5-dimethyl­pyrazol-1-yl)-2λ(5),4λ(5),6λ(5)-1,3,5,2,4,6-triaza­triphosphinine]tris­[cis-dichloridopalladium(II)]
title_sort [μ(3)-2,2,4,4,6,6-hexakis(3,5-dimethyl­pyrazol-1-yl)-2λ(5),4λ(5),6λ(5)-1,3,5,2,4,6-triaza­triphosphinine]tris­[cis-dichloridopalladium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961992/
https://www.ncbi.nlm.nih.gov/pubmed/21203062
http://dx.doi.org/10.1107/S1600536808023167
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